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首页> 外文期刊>Journal of Physical and Chemical Reference Data >Evaluated Chemical Kinetics Data for Reactions N(~2D),N(~2P), and N_2(A ~3sum_u~+) in the Gas Phase
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Evaluated Chemical Kinetics Data for Reactions N(~2D),N(~2P), and N_2(A ~3sum_u~+) in the Gas Phase

机译:评估用于反应N(〜2D),N(〜2P)和气相N_2(A〜3SUM_U +)的化学动力学数据

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摘要

Chemical kinetics data for the gas phase reactions of the first two electronically excited states of atomic nitrogen: N(~2D) and N(~2P), and of the first excited state of molecular nitrogen N_2(A ~3sum_u~+) are compiled and evaluated. The experimental data for 127 reactions are summarized, the experimental method and year of publication given, a recommended value given for the rate constant for each reaction at 298 K, and where possible, its temperature dependence. The reaction mechanisms are discussed within the limits of the available quantitative product yield data. The literature has been covered through early 1999. There are 94 references.
机译:用于原子氮的前两个电子激发态的气相反应的化学动力学数据:N(〜2D)和N(〜2P)和分子氮N_2(A〜3Sum_u〜+)的第一激发状态 并评估。 总结了127个反应的实验数据,所给予的实验方法和公布年份,每个反应的速率常数为298 k,在可能的情况下,其温度依赖性的推荐值。 在可用定量产物产量数据的限制范围内讨论反应机制。 文献已通过1999年初涵盖。有94个参考文献。

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