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Hot Corrosion Behavior of ZrB2-SiC-Graphite Composite in NaCl and Na2SO4 Molten Salts

机译:NaCl和Na2SO4熔盐中ZRB2-SiC-石墨复合材料的热腐蚀行为

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摘要

In the present work, the hot corrosion behavior of ZrB2-SiC-graphite (G) composite in different media at 900 and 1000 degrees C was investigated in detail. The results indicated that the ZrB2-SiC-G composite became slightly corroded in NaCl molten salts owing to the ZrB2 phase of the ZrB2-SiC-G composite being oxidized by oxygen molecules dissolved in the NaCl molten salts. However, the ZrB2-SiC-G composite underwent more severe corrosion in Na2SO4 molten salts, owing to the complex oxidation and sulfidation reaction of the ZrB2-SiC-G composite exposed to oxygen molecules and decomposition products of Na2SO4 at high temperature.
机译:在本作工作中,详细研究了在900和1000摄氏度下不同介质中的ZRB2-SiC-石墨(G)复合材料的热腐蚀行为。 结果表明,由于ZrB2-SiC-G复合物的ZrB2相通过溶解在NaCl熔盐中的氧分子氧化,ZRB2-SiC-G复合材料在NaCl熔融盐中略微腐蚀。 然而,由于ZrB2-SiC-G复合物在高温下暴露于氧分子和Na 2 SO 4的分解产物的复杂氧化和硫化反应,ZRB2-SiC-G复合材料在Na 2 SO 4熔融盐中进行了更严重的腐蚀。

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  • 作者单位

    Dalian Univ Technol Sch Aeronaut &

    Astronaut Fac Vehicle Engn &

    Mech State Key Lab Struct Anal Ind Equipment Dalian 116024 Peoples R China;

    Beijing Inst Aerosp Syst Engn Beijing 100076 Peoples R China;

    Beijing Inst Aerosp Syst Engn Beijing 100076 Peoples R China;

    Dalian Univ Technol Sch Aeronaut &

    Astronaut Fac Vehicle Engn &

    Mech State Key Lab Struct Anal Ind Equipment Dalian 116024 Peoples R China;

    Dalian Univ Technol Sch Aeronaut &

    Astronaut Fac Vehicle Engn &

    Mech State Key Lab Struct Anal Ind Equipment Dalian 116024 Peoples R China;

    Dalian Univ Technol Sch Aeronaut &

    Astronaut Fac Vehicle Engn &

    Mech State Key Lab Struct Anal Ind Equipment Dalian 116024 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 硅酸盐工业;
  • 关键词

    ZrB2-based composites; molten salts; hot corrosion; sulfidation;

    机译:ZRB2基复合材料;熔盐;热腐蚀;硫化;

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