Precision Multisegmented Macromolecular Lineups: A Display of Unique Control over Backbone Structure and Functionality

Driessen Frank; Du Prez Filip E.; Espeel Pieter

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Precision Multisegmented Macromolecular Lineups: A Display of Unique Control over Backbone Structure and Functionality

机译：精密的多段大分子产品：对骨干结构和功能的独特控制

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A practical synthesis of unique, precisely decorated, multisegmented block copolymers was elaborated via amine-thiol-ene conjugation. By mixing the thiolactone-acrylate heterotelechelic precursor polymer with selected amines, a library of multisegmented species was obtained, featuring a high level of control over backbone structure and spatial arrangement of side chain residues. Ranging from glycosylated to amphiphilic materials, these macromolecular lineups have been analyzed by LCxSEC DOSY-NMR, and DLS, revealing the particular properties of these macromolecular structures.

机译：通过胺-硫醇-烯键合，对独特，精确装饰的多链段嵌段共聚物进行了实用合成。通过将硫代内酯-丙烯酸酯杂telechelic前体聚合物与选定的胺混合，获得了多段物质的库，其特征是对主链结构和侧链残基的空间排列具有高度的控制力。从糖基化到两亲材料，这些大分子结构已通过LCxSEC DOSY-NMR和DLS分析，揭示了这些大分子结构的特殊性质。

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《ACS Macro Letters》 |2015年第6期|共4页
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Driessen Frank; Du Prez Filip E.; Espeel Pieter;
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1. Precision Multisegmented Macromolecular Lineups: A Display of Unique Control over Backbone Structure and Functionality [J] . Driessen Frank, Du Prez Filip E., Espeel Pieter ACS Macro Letters . 2015,第6期

机译：精密的多段大分子产品：对骨干结构和功能的独特控制
2. Unique combinations of macromolecular topology and functionality [J] . Casey L. Hudelson, Koji Yamauchi, Timothy E. Long Polymer Preprints . 2002,第2期

机译：大分子拓扑和功能的独特组合
3. A unique stepped multifunctionality of perfluorinated aryl compound and its versatile use in synthesizing grafted polymers with controlled structures and topologies [J] . Zhao Z., Ma X., Zhang A., Journal of Polymer Science, Part A. Polymer Chemistry . 2011,第11期

机译：全氟化芳基化合物独特的阶梯式多功能性及其在合成具有受控结构和拓扑结构的接枝聚合物中的广泛用途
4. Morphological Filtering based on the Minkowski Functionals in 3D for Segmentation of Macromolecular Structures in Intact Eukaryotic Cells Depicted by Cryo-Electron Tomography [C] . HF Boehm, F Jamitzki, RA Monetti, Society of Photo-Optical Instrumentation Engineers (SPIE);SPIE Proceedings . 2005

机译：基于Minkowski泛函的3D形态学滤波，用于冷冻电子断层扫描所描绘的完整真核细胞中大分子结构的分割
5. Structural and functional analysis of macromolecular machines involved in the protein quality control system. [D] . Iwanczyk, Jack. 2010

机译：蛋白质质量控制系统中涉及的大分子机器的结构和功能分析。
6. A Novel Allosteric Activator of Free Fatty Acid 2 Receptor Displays Unique Gi-functional Bias [O] . Daniele Bolognini, Catherine E. Moss, Karolina Nilsson, 2016

机译：游离脂肪酸2受体的新型变构活化剂显示独特的Gi功能偏差。
7. A novel allosteric activator of free fatty acid 2 receptor displays unique Gi-functional bias [O] . Bolognini, Daniele, Moss, Catherine E., Nilsson, Karolina, 2016

机译：一种新的游离脂肪酸2受体的变构激活剂显示出独特的Gi-功能偏差
8. Evaluation of Factors Unique to Multifunction Controls/Displays Devices [R] . Calhoun, G. L., Herron, E. L., Reising, J. M., 1980

机译：评估多功能控制/显示设备的独特因素

Precision Multisegmented Macromolecular Lineups: A Display of Unique Control over Backbone Structure and Functionality

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