Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide

Srinivas Abbina; Guodong Du

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Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide

机译：锌催化外消旋丙交酯的高等选择性开环聚合

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A family of chiral zinc amido-oxazolinate complexes are shown to be highly active and isoselective initiators for the ring-opening polymerization (ROP) of rac-lactide, yielding isotactic stereoblock polylactides (PLA) with P_m up to 0.91. This represents the highest isoselectivity observed with zinc-based catalysts for ROP of rac-lactide.

机译：手性酰胺基-恶唑啉酸锌络合物家族显示出是高活性和同选择引发剂，用于外消旋丙交酯的开环聚合（ROP），产生等规立构嵌段聚丙交酯（PLA），P_m高达0.91。这代表用锌基催化剂观察到的外消旋丙交酯的最高等选择性。

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《ACS Macro Letters》 |2014年第7期|共4页
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Srinivas Abbina; Guodong Du;
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正文语种 eng
中图分类有机化学;
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1. Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide [J] . Srinivas Abbina, Guodong Du ACS Macro Letters . 2014,第7期

机译：锌催化外消旋丙交酯的高等选择性开环聚合
2. Isoselective ring-opening polymerization and asymmetric kinetic resolution polymerization of rac-lactide catalyzed by bifunctional iminophosphorane-thiourea/urea catalysts [J] . Lv Chengdong, Zhou Li, Yuan Ruiting, New Journal of Chemistry . 2020,第4期

机译：双官能氨基磷酸硫醚 - 硫脲/脲催化剂催化的RAC-丙交酯的肌肉选择性开环聚合和不对称动力学分辨率聚合
3. Isoselective Ring-Opening Polymerization of rac-Lactide from Chiral Takemoto's Organocatalysts: Elucidation of Stereocontrol [J] . Orhan Beste, Tschan Mathieu J. -L., Wirotius Anne-Laure, ACS Macro Letters . 2018,第12期

机译：来自手性Takemoto的有机催化剂的RAC-Lactide的肌肉式开环聚合：阐明立体控制
4. NOVEL MONOMERIC CALCIUM, MAGNESIUM AND ZINC COMPLEXES AS INITIATORS FOR RING-OPENING POLYMERIZATION OF RAC-LACTIDE [C] . Liying Wang, Shaoan Xu, Shaodi Song, International symposium on polymer chemistry : Preprints. . 2010

机译：新颖的单价钙，镁和锌络合物作为引发剂对丙交酯的开环聚合反应
5. Fundamental studies on the reactivity of strained organometallic rings: A guide to the development of highly metallized polymers. [D] . Berenbaum, Andrea Lynn. 2002

机译：应变有机金属环反应性的基础研究：高度金属化聚合物发展的指南。
6. Zinc-Catalyzed Highly Isoselective Ring Opening Polymerizationof rac-Lactide [O] . Srinivas Abbina, Guodong Du, * -1

机译：锌催化的高等选择性开环聚合外消旋丙交酯
7. Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide [O] . Srinivas Abbina, Guodong Du 2014

机译：锌催化的RAC-丙交酯的高度肌肉式环开口聚合

Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide

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