Controllable Supramolecular Polymerization through Host-Guest Interaction and Photochemistry

Yang Liulin; Bai Yunhao; Tan Xinxin; Wang Zhiqiang; Zhang Xi

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Controllable Supramolecular Polymerization through Host-Guest Interaction and Photochemistry

机译：通过主体-客体相互作用和光化学可控的超分子聚合

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A new method for controllable supramolecular polymerization based on ABBA type monomer and cucurbit[8]uril monomer through host guest interaction and photochemistry is reported. The molecular weight and polydispersity of supramolecular polymers can be well controlled by tuning the molar ratio of these host and guest monomers or by tuning the isomer ratio of azobenzene groups in the guest monomers upon the competitive irradiation of lights. This research provides a general methodology for the control of supramolecular polymerization and the structure of supramolecular polymers.

机译：报道了一种基于ABBA型单体和葫芦[8]尿素单体通过宿主客体相互作用和光化学作用可控的超分子聚合的新方法。超分子聚合物的分子量和多分散性可以通过调节这些主体和客体单体的摩尔比或通过在竞争性光照射下调节客体单体中偶氮苯基的异构体比率来很好地控制。该研究提供了控制超分子聚合和超分子聚合物结构的通用方法。

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《ACS Macro Letters》 |2015年第6期|共5页
作者
Yang Liulin; Bai Yunhao; Tan Xinxin; Wang Zhiqiang; Zhang Xi;
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正文语种 eng
中图分类有机化学;
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专利

1. Controllable Supramolecular Polymerization through Host-Guest Interaction and Photochemistry [J] . Yang Liulin, Bai Yunhao, Tan Xinxin, ACS Macro Letters . 2015,第6期

机译：通过主体-客体相互作用和光化学可控的超分子聚合
2. Functional Supramolecular Polymeric Networks: The Marriage of Covalent Polymers and Macrocycle-Based Host-Guest Interactions [J] . Xia Danyu, Wang Pi, Ji Xiaofan, Chemical Reviews . 2020,第13期

机译：功能性超分子聚合物网络：共价聚合物的婚姻和基于宏观的主机互动
3. Controllable and large-scale supramolecular vesicle aggregation: orthogonal light-responsive host-guest and metal-ligand interactions [J] . Du Guangyan, Lou Lingyun, Guan Shuwen, Journal of Materials Chemistry, B. materials for biology and medicine . 2019,第26期

机译：可控和大规模的超分子囊泡聚集：正交光响应宿主和金属配体相互作用
4. Molecular Level Control Over Supramolecular Interactions Between Polymers, Cells and Nanocrystals [C] . Brett A. Helms, Dev S. Chaal, Harvey S. Chahal PMSE Symposia . 2012

机译：聚合物，细胞和纳米晶体之间超分子相互作用的分子水平控制
5. Supramolecular Host-Guest Interactions, Dynamics and Structure. [D] . Mugridge, Jeffrey Scott. 2010

机译：超分子宿主-客体相互作用，动力学和结构。
6. Supramolecular Chemistry And Self-assembly Special Feature: Supramolecular organic photochemistry: Control of covalent bondformation through noncovalent supramolecular interactions andmagnetic effects [O] . Nicholas J. Turro 2002

机译：超分子化学和自组装特殊功能：超分子有机光化学：共价键的控制通过非共价超分子相互作用形成磁效应
7. Cover Feature: Counter Cation Dependent and Stimuli Responsive Supramolecular Polymers Constructed by Calix4pyrrole Based Host-Guest Interactions (Eur. J. Org. Chem. 4/2019) [O] . Samet Yuvayapan, Abdullah Aydogan 2019

机译：覆盖特征：Calix 4吡咯基于宿主 - 访客互动构建的抗阳离子依赖性和刺激的超分子聚合物（EUR。J.Org.Chem.4 / 2019）

Controllable Supramolecular Polymerization through Host-Guest Interaction and Photochemistry

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