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Modern Applications of Matrix Isolation Technique to Investigation of Radical Species Generated in Atom-Molecular Chemical Reactions

机译:基质隔离 技术 的 现代应用 在 原子 - 分子 化学 反应产生的 自由基物种 调查

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摘要

The potential of using the translational mobility of hydrogen,oxygen and fluorine atoms in the crystals and solid matrices of inert gases for initiating solid-phase cryochemical reactions with their participation and solid matrices of inert gases for initiating solid-phase cryochemical reactions with their participation and for investigating the stabilised intermediate particles generated in these reactions is discussed.The mian spectroscopic methods used to study the stabilised particles are considered.The attention is focused on elucidation of spectroscopic characteristics required for reliable identification and determination of the structure of new reactive intermediates.Methodical approaches to the solutionof this problem are discussed.Examples of successful implementation of these approaches by various research groups are given.
机译:使用氢气,氧气和氟原子的平移迁移率的潜力和惰性气体的固体基质中,用于引发固相冷冻化学反应与其参与和固体基质的惰性气体,用于引发与他们的参与的固相冷冻化学反应 为了研究这些反应中产生的稳定的中间颗粒。用于研究稳定颗粒的Mian光谱方法是专注于阐明可靠鉴定和测定新的反应性中间体结构所需的光谱特性。方法 讨论了该问题解决方案的方法。给出了各种研究组成功实施这些方法的成功实施。

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  • 来源
    《Успехи химии》 |2003年第3期|共25页
  • 作者单位

    Institute of Problems of Chemical Physics Russian Academy of Sciences 142432 Chernogolovka Moscow Region Russian Federation;

    Institute of Problems of Chemical Physics Russian Academy of Sciences 142432 Chernogolovka Moscow Region Russian Federation;

    Institute of Problems of Chemical Physics Russian Academy of Sciences 142432 Chernogolovka Moscow Region Russian Federation;

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  • 正文语种 rus
  • 中图分类 化学;
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