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首页> 外文期刊>Chemical Engineering Science >Modeling the liquid–liquid extraction equilibrium of iron (III) with hydroxyoxime extractant and equilibrium-based simulation of counter-current copper extraction circuits
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Modeling the liquid–liquid extraction equilibrium of iron (III) with hydroxyoxime extractant and equilibrium-based simulation of counter-current copper extraction circuits

机译:用羟基肟提取剂和逆流铜萃取电路的羟基肟提取剂液 - 液提取平衡的液 - 液萃取平衡

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Highlights?A mechanistic model for iron (III) liquid–liquid extraction equilibrium is developed.?A useful empirical correlation for organic phase non-ideality is used.?The model is shown to be applicable over a wide range of operating conditions.?D-optimal design of experiments was used for model validation.?Influence of iron (III) on the copper liquid–liquid extraction process was analyzed.AbstractThe phase equilibrium in the loading and stripping stages of the liquid–liquid extraction of iron (III) with hydroxyoxime extractant in kerosene was studied over a wide range of hydroxyoxime extractant (Acorga M5640, 3–25vol–%) and iron (1.5–45g/L) concentrations. A mechanistic mathematical model explaining the phase equilibrium in the loading stage was developed and validated with new experimental data. The model
机译:<![cdata [ 亮点 开发了铁(III)液 - 液提取平衡的机械模型。 一个有用的经验使用有机相非理想性的相关性。 显示模型可在广泛的操作条件下适用。 D-Optimal设计用于MO del验证。 分析了铁(III)对铜液 - 液提取过程的影响。 抽象 液体装载和剥离阶段的相平衡研究了煤油中羟肟萃取剂的铁(III)的液体提取,在众多羟肟萃取剂(ACORGA M5640,3-25Vol%)和铁(1.5-45g / L)浓度上进行了研究。用新的实验数据开发并验证了解释加载阶段相平衡的机械数学模型。该模型

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