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首页> 外文期刊>Chemistry: A European journal >Molecular Encapsulation of Trimeric Chromium Carboxylate Clusters in Metal-Organic Frameworks and Propylene Sorption
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Molecular Encapsulation of Trimeric Chromium Carboxylate Clusters in Metal-Organic Frameworks and Propylene Sorption

机译：金属 - 有机骨架和丙烯吸附中三聚铬羧酸纤维簇的分子包封

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摘要

Oxo-bridged trimeric chromium acetate clusters [Cr_3O(OOCCH_3)_6(H_2O)_3]NO_3 have been encapsulated for the first time in the mesoporous cages of the chromium terephthalate MIL-101(Cr). The isolated clusters in MIL- 101(Cr) have increased affinity towards propylene compared to propane, due to generation of a new kind of pocket-based propylene-binding site, as supported by DFT calculations.
机译：氧气桥接三聚铬醋酸纤维簇[Cr_3O（OOCCH_3）_6（H_2O）_3] NO_3已在铬邻苯二甲酸铬MIL-101（CR）的中孔笼中首次包封。 由于通过DFT计算的基于袋丙烯结合位点，MIL-101（CR）中的分离的簇对丙烯的亲和力与丙烯相比增加了丙烯。

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  • 来源
    《Chemistry: A European journal》 |2019年第56期|共6页
  • 作者

    Sanil E. Sivan; Minhui Lee; Su-Kyung Lee; Ji Woong Yoon; Kiwoong Kim; Do- Young Hong; Kyung-Ho Cho; U-Hwang Lee; Jong-San Chang; Jaehoon Jung; Young Kyu Hwang;

  • 作者单位

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

    Department of Chemistry University of Ulsan 93 Daehak-ro Nam-gu Ulsan 44610 (Republic of Korea);

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

    Department of Chemistry University of Ulsan 93 Daehak-ro Nam-gu Ulsan 44610 (Republic of Korea);

    Research Center for Nanocatalysts Korea Research Institute of Chemical Technology (KRICT) Daejeon 305-600 (Korea);

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 应用化学;
  • 关键词

    encapsulation; isolation; metal-organic frameworks; molecular clusters; propylene sorption;

    机译：封装;隔离;金属有机框架;分子簇;丙烯吸附;

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