Decarboxylation as the Key Step in C-C Bond-Forming Reactions

Tuhin Patra; Debabrata Maiti

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Decarboxylation as the Key Step in C-C Bond-Forming Reactions

机译：脱羧作为C-C键形成反应的关键步骤

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C-C bond forming reactions incarnate the core of organic synthesis because of their fundamental applications to molecular diversity and complexity. In recent years, use of carboxylic acid as one of the coupling partners in place of conventional organometallic reagents has seen an upsurge due to its potency to generate similar organometallic intermediates after decarboxylation. This Review provides an overview on the most recent progress in the field of C-C bond formation involving decarboxylation as a key step. Different important developments, which are not included in earlier Reviews in this area, have been summarized with representative examples and discussions on their reaction mechanisms.

机译：C-C键形成反应是由于其基本应用与分子多样性和复杂性的基本应用，有机合成的核心。近年来，使用羧酸作为偶联伴侣的一个代替常规有机金属试剂，由于其效力，在脱羧后产生类似的有机金属中间体的效力。本综述概述了涉及脱羧作为关键步骤的C-C债券形成领域的最新进展情况。在这一领域的早期评论中，不包括在此领域的不同重要发展，已经总结在其反应机制的代表性和讨论中。

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来源
《Chemistry: A European journal》 |2017年第31期|共20页
作者
Tuhin Patra; Debabrata Maiti;
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作者单位

Department of Chemistry Indian Institute of Technology Bombay Powai Mumbai Maharashtra 400076 (India);

Department of Chemistry Indian Institute of Technology Bombay Powai Mumbai Maharashtra 400076 (India);

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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
carboxylic acids; C-C coupling; decarboxylation; synthetic methods;

机译：羧酸;C-C偶联;脱羧;合成方法;

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1. Decarboxylation as the Key Step in C-C Bond-Forming Reactions [J] . Tuhin Patra, Debabrata Maiti Chemistry: A European journal . 2017,第31期

机译：脱羧作为C-C键形成反应的关键步骤
2. Cationic Ir(Ⅲ) Alkylidenes Are Key Intermediates in C-H Bond Activation and C-C Bond-Forming Reactions [J] . Jesus Campos, Joaquin Lopez-Serrano, Eleuterio Alvarez, Journal of the American Chemical Society . 2012,第16期

机译：阳离子Ir（Ⅲ）亚烷基是C-H键活化和C-C键形成反应的关键中间体
3. Spiroazetidine-piperidine bromoiedane as a key modular template to access a variety of compounds via C-C and C-N bond-forming reactions [J] . Dilinie P. Fernando, Wenhua Jiao, Jana Polivkova Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2012,第47期

机译：螺旋氮杂环丁烷-哌啶溴代乙烷作为关键的模块化模板，可通过C-C和C-N键形成反应获得各种化合物
4. C-H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen-Deuterium Exchange and C-C Bond-Forming Reactions [C] . Steven R. Klei, Klan L. Tan, Jeffrey T. Golden, American Chemical Society National Meeting . 2004

机译：铱和铑配合物的C-H键活化：催化氢 - 氘交换和C-C键形成反应
5. I. Enantioselective total synthesis of quinine and quinidine. II. Thiourea-catalyzed enantioselective C-C bond-forming reactions. a. Catalytic asymmetric N-acyliminium ion cyclizations. b. Catalytic asymmetric aza-Baylis-Hillman reactions [D] . Raheem, Izzat Tiedje 2008

机译：I.奎宁和奎尼丁的对映选择性全合成。二。硫脲催化的对映选择性C-C键形成反应。一个。催化不对称N-酰亚胺离子环化。 b。催化不对称氮杂-Baylis-Hillman反应
6. Tandem application of C-C bond-forming reactions with reductive ozonolysis [O] . Rachel Willand-Charnley, Patrick H. Dussault -1

机译：与还原性臭氧分解C-C键形成反应的串联应用
7. Cationic Ir(III) Alkylidenes Are Key Intermediates in C-H Bond Activation and C-C Bond-Forming Reactions [O] . Campos Jesús, López-Serrano Joaquín, Álvarez Eleuterio, 2014

机译：阳离子Ir（III）炔烃是C-H键激活和C-C键形成反应的关键中间体

Decarboxylation as the Key Step in C-C Bond-Forming Reactions

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