Two 2D Zinc(II) Coordination Polymers and Their Orange IV Composites: Preparation, Structures, and Photocurrent Responses

Zhou Xuan; Liu Dan; Lang Fei-Fan; Ren Zhi-Gang; Lang Jian-Ping

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Two 2D Zinc(II) Coordination Polymers and Their Orange IV Composites: Preparation, Structures, and Photocurrent Responses

机译：两种2D锌（II）配位聚合物及其橙色IV复合材料：制备，结构和光电流反应

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Reactions of Zn(OAc)(2)center dot 2H(2)O with N-1,N-4-bis(5-fluoropyridin-3-yl)succinamide (bfps) and 1,2,3-benzenetricarboxylic acid (1,2,3-H3BTC) or 1,3,5-benzenetricarboxylic acid (1,3,5-H3BTC) under hydrothermal conditions produce two Zn(II)-based coordination polymers (CPs), {[Zn-3(bfps)(1,2,3-BTC)2(H2O)6]center dot 4H(2)O}(n) (1 center dot 4H(2)O) and {[Zn(bfps)(1,3,5-HBTC)]center dot H2O} (2-H2O). Both compounds show two-dimensional layer structures derived from interconnecting dinuclear [Zn-2(1,2,3-BTC)(2)(H2O)(2)] units through the bfps bridges and the [Zn(H2O)(4)] species (1.4H(2)O) or interlinking dinuclear [Zn-2(1,3,5-HBTC)(2)] units via pairs of bfps bridges and pairs of 1,3,5-HBTC dianions (2 center dot H2O). They display high absorptive capacities toward Orange IV (OIV) in water, i.e., 718 mg-g(-1) (1. 4H(2)O) and 794 mg.g(-1) (2H(2)O), respectively. The resulting CP-OIV composites with the chemical formulas of 1.2.0OIW (3) and 2-1.1OIV center dot 2.5H(2)O (4) exhibit enhanced photocurrent responses in relation to those of the two precursors.

机译：Zn（OAC）（2）中心点2H（2）o与N-1，N-4-双（5-氟吡啶-3-基）琥珀酰胺（BFP）和1,2,3-苯甲酸（1水热条件下的2,3-H 3 -BTC）或1,3,5-苯甲基酸（1,3,5-H3BTC）产生两种Zn（II）的配位聚合物（CPS），{[Zn-3（BFP）（1,2,3-BTC）2（H2O）6]中心点4H（2）O}（n）（1中心点4h（2）o）和{[Zn（BFPS）（1,3,5- HBTC）]中心点H2O}（2-H2O）。两种化合物都显示出通过BFPS网桥和[Zn（H2O）（4）衍生自互连的二核[Zn-2（1,2,3-BTC）（2）（2）]单元的二维层结构。 ]通过对BFPS桥和1,3,5-HBTC探剂的对（2中心的对（2中心点H2O）。它们对水中的橙色IV（OIV）显示出高吸收能力，即718mg-G（-1）（1.4H（2）o）和794 mg.g（-1）（2h（2）o），分别。得到的CP-OIV复合材料，具有1.2.0℃和2-1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1.1℃的CP-OIV复合材料表现出与两种前体的增强的光电流反应相关。

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《Crystal growth & design》 |2019年第1期|共8页
作者
Zhou Xuan; Liu Dan; Lang Fei-Fan; Ren Zhi-Gang; Lang Jian-Ping;
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Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

Univ Sheffield Dept Chem Brook Hill Sheffield S3 7HF S Yorkshire England;

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

Soochow Univ Coll Chem Chem Engn &

Mat Sci Suzhou 215123 Jiangsu Peoples R China;

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中图分类晶体学;
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Two 2D Zinc(II) Coordination Polymers and Their Orange IV Composites: Preparation, Structures, and Photocurrent Responses

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