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Exploring Anisotropy on Oriented Wafers of MAPbBr(3) Crystals Grown by Controlled Antisolvent Diffusion

机译:通过受控的防溶剂扩散探索导向晶圆面向MAPBBBR(3)晶体的各向异性

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摘要

The emergence of organic-inorganic halide perovskites has reformed the research status of optoelectronics to a great extent. The bulk single crystals of halide perovskite, which in theory reflect the intrinsic physical properties of the material, are however hard to integrate into functional devices. Just as in the case that silicon wafers have revolutionized modern industries including electronics and solar cells, the availability of perovskite crystal wafers may pave the way to functional devices. Here we designed a new settled temperature and controlled antisolvent diffusion system to precisely control all key factors that affect the supersaturation metastable zone during the crystal growth process, to grow MAPbBr(3) single crystals more than 50 mm in size. Second, we fabricated MAPbBr(3) single crystal wafers with different orientations, specifically, the (100), (010), (001), (110), and (111) wafers, with high crystalline quality (half-peak width of rocking curve of 60-100 arc sec). Some key parameters were measured and compared on the wafers, where the results hint that anisotropy of carrier transport may exist for this pseudocubic structure. We hope the availability of oriented single-crystal wafers can provide more scientists the materials and devices to clarify the debatable physicochemical properties and to integrate the wafers as active layers or substrates in optoelectronic devices.
机译:有机无机卤化物钙锌矿的出现在很大程度上改革了光电子的研究状态。卤化物钙钛矿的散装单晶,从理论反映了材料的内在物理性​​质,然而难以集成到功能装置中。正如硅晶片彻底改变了现代行业,包括电子和太阳能电池的情况一样,佩罗夫斯库茨晶晶晶片的可用性可能会铺平到功能装置。在这里,我们设计了一种新的沉降温度和受控的防溶剂扩散系统,精确地控制了在晶体生长过程中影响超饱和亚稳态区的所有关键因素,以生长Mapbbr(3)单晶的尺寸超过50mm。其次,我们用不同取向制造MAPBBR(3)单晶晶片,具体地,(100),(010),(001),(110)和(111)晶片,具有高晶体质量(半峰宽度摇摆曲线为60-100弧秒)。测量并比较晶片上的一些关键参数,其中结果提示该假结构结构可能存在载体传输的各向异性。我们希望面向定向的单晶晶片的可用性可以提供更多科学家的材料和装置,以阐明脱脂物理化学性质,并将晶片整合为光电器件中的有源层或基板。

著录项

  • 来源
    《Crystal growth & design》 |2018年第11期|共9页
  • 作者单位

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

    Shandong Univ State Key Lab Crystal Mat Jinan 250100 Shandong Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 晶体学;
  • 关键词

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