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首页> 外文期刊>Crystal growth & design >Controlling the Orientation of Metal–Organic Framework Crystals by an Interfacial Growth Approach Using a Metal Ion-Doped Polymer Substrate
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Controlling the Orientation of Metal–Organic Framework Crystals by an Interfacial Growth Approach Using a Metal Ion-Doped Polymer Substrate

机译：使用金属离子掺杂聚合物基材通过界面生长方法控制金属 - 有机框架晶体的取向

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src="http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/cgdefu/2018/cgdefu.2018.18.issue-1/acs.cgd.7b01402/20171227/images/medium/cg-2017-01402p_0009.gif">Highly oriented three-dimensional metal–organic framework (MOF) crystals with a pillared-layer structure were prepared on a metal ion-doped polymer substrate. This approach allowed the formation of MOF crystals with controlled crystalline orientation in a one-pot reaction facilitated by the control of the chemical interaction between the framework components and polymer substrate. Further, this approach provides a new concept for the one-pot synthesis of oriented MOF crystals and furthers the fundamental understanding of the crystal growth mechanism based on self-assembly processes on two-dimensional support substrates.
机译：src =“http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/cgdefu/2018/cgdefu.2018.18.issue-1/acs.cgd.7b01402/20171227/images/medium 在金属离子掺杂的聚合物基材上制备具有柱形层结构的温度化的三维金属 - 有机框架（MOF）晶体。 这种方法使得通过控制框架组分和聚合物基材之间的化学相互作用，在一锅反应中形成具有受控结晶取向的MOF晶体。 此外，这种方法为取向的MOF晶体的单盆合成提供了一种新的概念，并将基于自组装过程对二维支撑基板上的自组装过程来说是对晶体生长机制的基本理解。

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  • 来源
    《Crystal growth & design》 |2018年第1期|共7页
  • 作者

    Takashi Ohhashi; Takaaki Tsuruoka; Seiya Fujimoto; Yohei Takashima; Kensuke Akamatsu;

  • 作者单位

    Department of Nanobiochemistry Frontiers of Innovative Research in Science and Technology (FIRST) Konan University 7-1-20 Minatojimaminami Chuo-ku Kobe 650-0047 Japan;

    Department of Nanobiochemistry Frontiers of Innovative Research in Science and Technology (FIRST) Konan University 7-1-20 Minatojimaminami Chuo-ku Kobe 650-0047 Japan;

    Department of Nanobiochemistry Frontiers of Innovative Research in Science and Technology (FIRST) Konan University 7-1-20 Minatojimaminami Chuo-ku Kobe 650-0047 Japan;

    Department of Nanobiochemistry Frontiers of Innovative Research in Science and Technology (FIRST) Konan University 7-1-20 Minatojimaminami Chuo-ku Kobe 650-0047 Japan;

    Department of Nanobiochemistry Frontiers of Innovative Research in Science and Technology (FIRST) Konan University 7-1-20 Minatojimaminami Chuo-ku Kobe 650-0047 Japan;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 晶体学;
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