Incorporation of Clathrochelate-Based Metalloligands in Metal-Organic Frameworks by Solvent-Assisted Ligand Exchange

Planes Ophelie M.; Schouwink Pascal A.; Bila Jose L.; Fadaei-Tirani Farzaneh; Scopelliti Rosario; Severin Kay

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Incorporation of Clathrochelate-Based Metalloligands in Metal-Organic Frameworks by Solvent-Assisted Ligand Exchange

机译：通过溶剂辅助配体交换掺入金属有机骨架中的Clathrochelate基金属

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Iron(II) cage complexes with terminal 4-pyridyl groups can be incorporated in metal-organic frameworks (MOFs) via solvent-assisted ligand exchange (SALE). Paddle -wheeled MOFs with N,N'-di-4-pyridylnaphthalenete-tracarboxydiimide pillars were used as starting materials. Pillar exchange was nearly quantitative, despite the fact that the cage complexes are long (similar to 15 angstrom) and sterically demanding. The reactions provide products of high crystallinity, and the structures of daughter MOFs were determined by single crystal X-ray diffraction. The crystallographic analyses showed that some of the SALE experiments led to topological changes of the MOF structures.

机译：具有末端4-吡啶基的铁（II）笼式复合物可通过溶剂辅助的配体交易（销售）掺入金属 - 有机骨架（MOF）中。用N，N'-DI-4-吡啶基萘葡萄球菌 - Tracarboxydiidimide柱的桨式桨式MOF作为原料。尽管笼子复合物长（类似于15埃）和空心苛刻的情况，但支柱交换几乎是定量的。反应提供高结晶度的产物，并且通过单晶X射线衍射测定女儿MOF的结构。结晶分析表明，一些销售实验导致了MOF结构的拓扑变化。

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《Crystal growth & design》 |2020年第3期|共6页
作者
Planes Ophelie M.; Schouwink Pascal A.; Bila Jose L.; Fadaei-Tirani Farzaneh; Scopelliti Rosario; Severin Kay;
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作者单位

Ecole Polytech Fed Lausanne Inst Chem Sci &

Engn CH-1015 Lausanne Switzerland;

Ecole Polytech Fed Lausanne Inst Chem Sci &

Engn CH-1015 Lausanne Switzerland;

Ecole Polytech Fed Lausanne Inst Chem Sci &

Engn CH-1015 Lausanne Switzerland;

Ecole Polytech Fed Lausanne Inst Chem Sci &

Engn CH-1015 Lausanne Switzerland;

Ecole Polytech Fed Lausanne Inst Chem Sci &

Engn CH-1015 Lausanne Switzerland;

Ecole Polytech Fed Lausanne Inst Chem Sci &

Engn CH-1015 Lausanne Switzerland;

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正文语种 eng
中图分类晶体学;
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专利

1. Incorporation of Clathrochelate-Based Metalloligands in Metal-Organic Frameworks by Solvent-Assisted Ligand Exchange [J] . Planes Ophelie M., Schouwink Pascal A., Bila Jose L., Crystal growth & design . 2020,第3期

机译：通过溶剂辅助配体交换掺入金属有机骨架中的Clathrochelate基金属
2. Water stabilization of Zr-6-based metal-organic frameworks via solvent-assisted ligand incorporation [J] . Deria Pravas, Chung Yongchul G., Snurr Randall Q., Chemical science . 2015,第9期

机译：通过溶剂辅助配体的结合使Zr-6基金属有机骨架水稳定
3. A solvent-assisted ligand exchange approach enables metal-organic frameworks with diverse and complex architectures [J] . Dongbo Yu, Qi Shao, Qingjing Song, Nature Communications . 2020,第1期

机译：溶剂辅助配体交换方法使金属有机框架具有多样化和复杂的架构
4. Luminescent Properties of Lanthanide-Based Metal-Organic Frameworks with Rigid Tritopic Carboxylate Ligands [C] . Hani Nasser Abdelhamid, Magdalena Wilk-Kozubek, Xiaodong Zou Rare Earth Research Conference . 2019

机译：镧系元素 - 有机骨架的发光性能刚性氚型羧酸盐配体
5. Rotaxane Ligands for Incorporation into Metal-Organic Framework Materials [D] . Gholami, Ghazale. 2017

机译：用于有机金属骨架材料的轮烷配体
6. Water stabilization of Zr6-based metal–organic frameworks via solvent-assisted ligand incorporation [O] . Pravas Deria, Yongchul G. Chung, Randall Q. Snurr, 2015

机译：通过溶剂辅助配体的结合使Zr6基金属有机框架的水稳定性
7. Incorporation of Clathrochelate-Based Metalloligands in Metal–Organic Frameworks by Solvent-Assisted Ligand Exchange [O] . Ophélie M. Planes, Pascal A. Schouwink, José L. Bila, 2020

机译：通过溶剂辅助配体交换掺入金属有机骨架中的Clathrochelate基金属
8. Water Stabilization of Zr6-Based Metal-Organic Frameworks via Solvent-Assisted Ligand Incorporation. [R] . Deria, P., Chung, Y. G., Snurr, R. Q., 2015

机译：通过溶剂辅助配体加入Zr6基金属有机骨架的水稳定性。

Incorporation of Clathrochelate-Based Metalloligands in Metal-Organic Frameworks by Solvent-Assisted Ligand Exchange

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