...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Crystal growth & design >A New KBBF-Family Nonlinear Optical Material with Strong Interlayer Bonding
【24h】

A New KBBF-Family Nonlinear Optical Material with Strong Interlayer Bonding

机译：一种新的KBBF系列非线性光学材料，具有强相粘接

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

A new beryllium-free borate Rb3Ba3Li2Al4B6O20F features a layered structure analogous to that of the solely available deep-ultraviolet nonlinear optical (NLO) material KBe2BO3F2 (KBBF), and thus preserves its outstanding linear and nonlinear optical properties to a great extent. Furthermore, the interlayer bonding in Rb3Ba3Li2Al4-B6O20F is significantly reinforced, with a magnitude of more than 15.6 times that of KBBF. As a result, a bulk Rb3Ba3Li2Al4B6O20F crystal is successfully grown in the preliminary experiments. The result demonstrates that the Rb3Ba3Li2Al4B6O20F crystal may have no (or only a tiny) layering growth habit, which severely hinders the practical applications of KBBF. Notably, Rb3Ba3Li2Al4B6O20F overcomes the structural instability problem present in the notable KBBF-family member Sr2Be2B2O7. These results make Rb3Ba3Li2Al4B6O20F a promising candidate for the next generation of deep-ultraviolet NLO materials. First-principles calculations are performed to elucidate the optical properties and structural stability.
机译：一种新的无铍硼酸硼酸RB3BA3LI2AL4B6O20F具有类似于仅可用的深紫外线非线性光学（NLO）材料KBE2BO3F2（KBBF）的层状结构，因此在很大程度上保持其优异的线性和非线性光学性能。此外，RB3BA3LI2AL4-B6O20F中的中间层键合显着增强，其大小超过KBBF的15.6倍。结果，在初步实验中成功地生长了散装RB3Ba3Li2Al4B6O20F晶体。结果表明，RB3BA3LI2AL4B6O20F晶体可能没有（或仅为微小的）分层生长习性，这严重阻碍了KBBF的实际应用。值得注意的是，RB3BA3LI2AL4B6O20F克服了标记KBBF系列成员SR2BE2B2O7中存在的结构不稳定问题。这些结果使RB3BA3LI2AL4B6O20F成为下一代深层紫外线材料的有希望的候选者。进行第一原理计算以阐明光学性质和结构稳定性。

著录项

  • 来源
    《Crystal growth & design》 |2017年第8期|共6页
  • 作者

    Shen Yaoguo; Zhao Sangen; Yang Yi; Cao Liling; Wang Zujian; Zhao Bingqing; Sun Zhihua; Lin Zheshuai; Luo Junhua;

  • 作者单位

    Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

    Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

    Chinese Acad Sci Tech Inst Phys &

    Chem Beijing Ctr Crystal R&

    D Key Lab Funct Crystals &

    Laser Technol Beijing 100190 Peoples R China;

    Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

    Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

    Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

    Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

    Chinese Acad Sci Tech Inst Phys &

    Chem Beijing Ctr Crystal R&

    D Key Lab Funct Crystals &

    Laser Technol Beijing 100190 Peoples R China;

    Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 晶体学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号