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Determination of the True Lateral Grain Size in Organic-Inorganic Halide Perovskite Thin Films

机译:有机 - 无机卤化物钙钛矿薄膜真正横向粒度的测定

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In this letter, methylammonium lead iodide (MAPbI(3)) thin films were examined via piezoresponse force microscopy (PFM) and nanoindentation (NI) to determine if long-range atomic order existed across the full width and depth of the apparent grains. From the PFM, the piezoelectric response of the films was strongly correlated with low-index planes of the crystal structure and ferroelastic. domains in macroscale solution-grown MAPbI(3) crystals, which implied long-range order near the top surface. From the NI, it was found that the induced cracks were straight and extended across the full width of the apparent grains, which indicated that the long-range order was pot limited to the near-surface region, but extended through the film thickness. Interestingly, the two MAPbI(3) processes examined resulted in subtle differences in the extracted electro-mechanical and fracture properties, but exhibited similar power conversion efficiencies of >17% in completed devices.
机译:在这封信中,通过压电响应力显微镜(PFM)和纳米凸缘(Ni)检查甲基铅碘化物(MAPBI(3))薄膜,以确定是否存在在表观颗粒的全宽和深度上存在的远程原子序。 从PFM,薄膜的压电响应与晶体结构的低折射率平面强烈地相关。 宏观解决方案的域在宏观上生长的MAPBI(3)晶体,其暗示顶部表面附近的远程顺序。 从NI来看,发现诱导的裂缝直线并延伸穿过表观晶粒的全宽,这表明远程顺序被限制在近表面区域,而是通过膜厚度延伸。 有趣的是,检查的两种MAPBI(3)过程导致提取的电力和骨折性能下细微差异,但在完成的装置中表现出类似的功率转化效率> 17%。

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