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Microfluidic Fabrication of Phase-Inverted Microcapsules with Asymmetric Shell Membranes with Graded Porosity

机译:具有梯度孔隙率的不对称壳膜的相倒置微胶囊的微流体制造

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摘要

Microcapsules with liquid cores and solid shells are attractive as dispersible protective micron-sized containers. Applications that rely on molecular mass transport often require a combination of size selectivity, high permeability, and mechanical stability. Capsule architectures that combine all these features represent a material property, design, and fabrication challenge. In this work, the design of an asymmetric microcapsule shell architecture is reported to achieve a good combination of the desired features. Poly(methyl methacrylate) phase-inverted microcapsules featuring an asymmetric graded macroporous shell covered with a dense skin separation layer are obtained from water-in-oil-in-water double emulsion drops that are phase-inverted in a water-based coagulation bath. The phase-inverted microcapsules exhibit good mechanical stability and allow for high permeability of its shell membrane with molecular size dependence.
机译:None

著录项

  • 来源
    《ACS Macro Letters》 |2021年第1期|共6页
  • 作者单位

    John A. Paulson School of Engineering and Applied Sciences Harvard University;

    John A. Paulson School of Engineering and Applied Sciences Harvard University;

    John A. Paulson School of Engineering and Applied Sciences Harvard University;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 有机化学;
  • 关键词

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