Structures of Biomolecular Ions in the Gas Phase Probed by Infrared Light Sources

Corey N. Stedwell; Johan F. Galindo; Adrian E. Roitberg; Nicolas C. Polfer

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Structures of Biomolecular Ions in the Gas Phase Probed by Infrared Light Sources

机译：红外光源探测气相中生物分子离子的结构

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Infrared (IR) spectroscopy of biomolecular ions combines mass spectrometry's high sensitivity and ability to analyze complex mixtures with the enhanced structural information available from vibrational spectroscopy. IR spectroscopy is in principle well placed to distinguish isomers and allow chemical classification of unknown molecules. This review gives an outline of current instrumentation, spectroscopic approaches, and potential bottlenecks. We discuss the most promising applications in bioanalytical mass spectrometry in view of recent experimental results, as well as future applications based on bioinformatics.

机译：生物分子离子的红外（IR）光谱结合了质谱仪的高灵敏度和分析复杂混合物的能力以及振动光谱学提供的增强的结构信息。原则上，红外光谱法可以很好地区分异构体并允许对未知分子进行化学分类。这篇综述概述了当前的仪器，光谱方法和潜在的瓶颈。鉴于最近的实验结果以及基于生物信息学的未来应用，我们将讨论生物分析质谱法中最有希望的应用。

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《Annual Review of Analytical Chemistry》 |2013年第null期|共19页
作者
Corey N. Stedwell; Johan F. Galindo; Adrian E. Roitberg; Nicolas C. Polfer;
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正文语种 eng
中图分类物理化学计量;
关键词
infrared spectroscopy; mass spectrometry; biomolecules; chemical moieties; multiplexing; tagging;

机译：红外光谱;质谱;生物分子;化学部分;多路复用;标记;

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1. Structures of Biomolecular Ions in the Gas Phase Probed by Infrared Light Sources [J] . Corey N. Stedwell, Johan F. Galindo, Adrian E. Roitberg, Annual Review of Analytical Chemistry . 2013,第Null期

机译：红外光源探测气相中生物分子离子的结构
2. Good vibrations: probing biomolecular structure and interactions through spectroscopy in the gas phase [J] . J.P. Simons Molecular physics . 2009,第23a24期

机译：良好的振动：通过气相色谱法探测生物分子结构和相互作用
3. Probing the structures of gas-phase rhodium cluster cations by far-infrared spectroscopy [J] . Harding D.J., Gruene P., Haertelt M., The Journal of Chemical Physics . 2010,第21期

机译：用远红外光谱探测气相铑簇阳离子的结构
4. Gas phase structure of calcium(II)-catechol complexes probed by infrared spectroscopy [C] . Matias Butler, Pau Arroyo Manez, Philippe Maitre, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2012

机译：通过红外光谱法探测的钙（II）的气相结构 - CaTechol复合物
5. An investigation of the source of the far infrared radiation in spiral galaxies using near infrared hydrogen recombination lines as a probe of star formation. [D] . Jones, Lauren Valery. 2000

机译：使用近红外氢重组线作为恒星形成的探针，对螺旋星系中的远红外辐射源进行了研究。
6. Blackbody Infrared Radiative Dissociation of Bradykinin and Its Analogues: Energetics Dynamics and Evidence for Salt-Bridge Structures in the Gas Phase [O] . Paul D. Schnier, William D. Price, Rebecca A. Jockusch, -1

机译：缓激肽及其类似物的黑体红外辐射解离：气相中盐桥结构的能量学动力学和证据
7. Good Vibrations: Probing Biomolecular Structure and Interactions through Spectroscopy in the Gas Phase [O] . Simons, J.P. 2009

机译：良好的振动：通过气相色谱探测生物分子结构和相互作用
8. Infrared Multiphoton Dissociation of Some Oxygen-Containing Hydrocarbon Ions. Differentiation of Isomeric Ion Structures in the Gas Phase [R] . Baykut, G., Watson, C. H., Weller, R. R., 1985

机译：一些含氧烃离子的红外多光子解离。气相中异构离子结构的分化

Structures of Biomolecular Ions in the Gas Phase Probed by Infrared Light Sources

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