Polystyrene-Anchored Cinchona Ammonium Salts:Easily Recoverable Phase-Transfer Catalysts for the Asymmetric Synthesis of alpha-Amino Acids

Rafael Chinchilla; Patricia Mazon; Carmen Najera

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Polystyrene-Anchored Cinchona Ammonium Salts:Easily Recoverable Phase-Transfer Catalysts for the Asymmetric Synthesis of alpha-Amino Acids

机译：聚苯乙烯锚定的金鸡纳铵盐：α氨基酸不对称合成的易于回收的相转移催化剂

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摘要

Cinchonidine,epicinchonidine,cinchonine or quinine have been N-anchored to cross-linked polystyrene (Merrifield resin) or grafted polystyrene (Syn-Phase~(TM) Lanterns) affording polymer-supported chi-ral ammonium salts which are employed as phase-transfer catalysts in the asymmetric alkylation of N-(diphenylmethylene)glycine esters.These new polymeric catalysts can be easily recovered after the reaction by simple filtration and reused.

机译：辛可尼定，表氯可定，辛可宁或奎宁已被N锚定在交联的聚苯乙烯（Merrifield树脂）或接枝的聚苯乙烯（Syn-PhaseTM灯笼）上，提供了聚合物支撑的手性铵盐，可将其用作相转移N-（二苯基亚甲基）甘氨酸酯的不对称烷基化反应中的这些催化剂。这些新的聚合催化剂在反应后可通过简单过滤轻松回收并重复使用。

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《Advanced synthesis & catalysis》 |2004年第10期|共9页
作者
Rafael Chinchilla; Patricia Mazon; Carmen Najera;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
alkylation; amino acids; ammonium salts; asymmetric synthesis; C-C bond formation; organic catalysis; phase-transfer catalysis;

机译：烷基化;氨基酸;铵盐;不对称合成;C-C键形成;有机催化;相转移催化;

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1. Polystyrene-Anchored Cinchona Ammonium Salts:Easily Recoverable Phase-Transfer Catalysts for the Asymmetric Synthesis of alpha-Amino Acids [J] . Rafael Chinchilla, Patricia Mazon, Carmen Najera Advanced synthesis & catalysis . 2004,第9a10期

机译：聚苯乙烯锚定的金鸡纳铵盐：α氨基酸不对称合成的易于回收的相转移催化剂
2. Asymmetric synthesis of alpha-amino acids using polymer-supported Cinchona alkaloid-derived ammonium salts as chiral phase-transfer catalysts [J] . Chinchilla R., Najera C., Mazon P. Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2000,第16期

机译：使用聚合物负载的金鸡纳生物碱衍生的铵盐作为手性相转移催化剂的α-氨基酸的不对称合成
3. Improved conditions for the asymmetric synthesis of alpha-amino acids using Cinchona-derived anthracenylmethyl ammonium salts as chiral phase-transfer organocatalysts [J] . Chinchilla R, Najera C, Ortega FJ Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2006,第24期

机译：使用金鸡纳衍生的蒽基甲基铵盐作为手性相转移有机催化剂的α-氨基酸不对称合成的改进条件
4. Asymmetric Synthesis of α-Amino Acids Using Polymer-Supported Cinchona Ammonium Salts as Phase-Transfer Catalysts [C] . Rafael Chinchilla, Carmen Najera Asymmetric synthesis and application of α-amino acids . 2007

机译：以聚合物为载体的金鸡纳铵盐为相转移催化剂不对称合成α-氨基酸
5. Novel cinchona alkaloid derived ammonium salts as phase-transfer catalysts for the asymmetric synthesis of beta-hydroxy alpha-amino acids via aldol reactions and total synthesis of celogentin C. [D] . Ma, Bing. 2009

机译：新型金鸡纳生物碱衍生的铵盐作为相转移催化剂，用于通过醛醇缩合反应不对称合成β-羟基α-氨基酸和全合成celogentinC。
6. Polymer-Supported Cinchona Alkaloid-Derived Ammonium Salts as Recoverable Phase-Transfer Catalysts for the Asymmetric Synthesis of α-Amino Acids [O] . Rafael Chinchilla, Patricia Mazón, Carmen Nájera 2004

机译：聚合物负载的金鸡纳生物碱衍生的铵盐作为可回收的不对称合成α-氨基酸的相转移催化剂
7. Polymer-Supported Cinchona Alkaloid-Derived Ammonium Salts as Recoverable Phase-Transfer Catalysts for the Asymmetric Synthesis of α-Amino Acids† [O] . Rafael Chinchilla, Patricia Mazón, Carmen Nájera 2015

机译：聚合物支持的金鸡纳生物碱衍生的铵盐作为可回收的相转移催化剂用于α-氨基酸的不对称合成†

Polystyrene-Anchored Cinchona Ammonium Salts:Easily Recoverable Phase-Transfer Catalysts for the Asymmetric Synthesis of alpha-Amino Acids

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