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首页> 外文期刊>Inorganic Chemistry Communications >Molecular Structureof [In_2(#mu#, eta~1-OR)(#mu#, eta~2-OR)(eta~2-OR)_3 (eta~1-OR)] R = C_2H_4NMe_2, a pincer ligand
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Molecular Structureof [In_2(#mu#, eta~1-OR)(#mu#, eta~2-OR)(eta~2-OR)_3 (eta~1-OR)] R = C_2H_4NMe_2, a pincer ligand

机译:[In_2(#mu#,eta〜1-OR)(#mu#,eta〜2-OR)(eta〜2-OR)_3(eta〜1-OR)的分子结构R = C_2H_4NMe_2,一种钳位配体

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摘要

Functional indium [In(OR)_3]_m alkoxides (R = C_2H_4OM, C_2H_4NMe_2) have been obtained by alcoholysis of In[N(SiMe_3)_2]_3 and characterised by elemental analysis, FT-RI and NMR spectroscopy. The 2-dimethylaminoethoxide was characterised by X-ray diffraction. it corresponds to the association of two InO_6 octahedra giving the unsymmetrical dimer [In_2(#mu#, eta~1-OR)(#mu#, eta~2-OR) (eta~2-OR)_3(eta~1-OR)] (2). 2 was used as a pincer ligand toward Cu(acac)_2.
机译:通过In [N(SiMe_3)_2] _3的醇解反应获得了功能性铟[In(OR)_3] _m醇盐(R = C_2H_4OM,C_2H_4NMe_2),并通过元素分析,FT-RI和NMR光谱表征。通过X射线衍射表征2-二甲基氨基乙醇。它对应于两个InO_6八面体的关联,给出不对称的二聚体[In_2(#mu#,eta〜1-OR)(#mu#,eta〜2-OR)(eta〜2-OR)_3(eta〜1-或]](2)。 2用作对Cu(acac)_2的钳位配体。

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