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首页> 外文期刊>Inorganic Chemistry Communications >Solvothermal synthesis, structure and properties of a new 3-D Cu(I)-Gd(III)heterometallic coordination framework
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Solvothermal synthesis, structure and properties of a new 3-D Cu(I)-Gd(III)heterometallic coordination framework

机译:新型3-D Cu(I)-Gd(III)杂金属配位骨架的溶剂热合成,结构和性质

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摘要

A new 3d-4f heterometallic coordination polymer, [CuGd2(INAIP)3(HCOO)(H2O)3]·3H2O (1), [H2INAIP = 5-(isonicotinamido)isophthalic acid] has been synthesized and characterized by single crystal X-ray diffraction analysis. The results of structural analyses show that 1 has a two-fold interpenetrated 3D coordination framework with a rare sqc27 topology. In addition, thermogravimetric and magnetic properties were also investigated.
机译:合成了一种新型的3d-4f杂金属配位聚合物[CuGd2(INAIP)3(HCOO)(H2O)3]·3H2O(1),[H2INAIP = 5-(异烟酰胺基)间苯二甲酸],并通过单晶X-进行了表征射线衍射分析。结构分析的结果表明,1具有双重互穿的3D协调框架,并具有罕见的sqc27拓扑。另外,还研究了热重和磁性能。

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