Synthesis,structure and second harmonic generation of novel inorganic-organic hybrid,(p-cyano-1-hydrogenpyridinium)_2CdI_4

Peng Ren; Jingui Qin; Tao Liu; Shiwei Zhang

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Synthesis,structure and second harmonic generation of novel inorganic-organic hybrid,(p-cyano-1-hydrogenpyridinium)_2CdI_4

机译：新型无机-有机杂化物（对氰基-1-氢吡啶鎓）_2CdI_4的合成，结构与二次谐波生成

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摘要

A novel noncentrosymmetric inorganic-organic hybrid compound,(CHP)_2CdI_4 (CHP = 4-cyano-1-hydrogen pyridinium),has been synthesized and the structure contains randomly arrayed CHP cations with two possible orientations,which is stabilized via hydrogen-bonding interactions with isolated and perfectly packed CdI_4~(2-) tetrahedrons,showing a moderate second harmonic generation (SHG) of about three times as large as that of KDP.

机译：合成了一种新型的非中心对称无机-有机杂化化合物（CHP）_2CdI_4（CHP = 4-cyano-1-hydrogen pyridinium），该结构包含随机排列的具有两个可能方向的CHP阳离子，并通过氢键相互作用使其稳定化。具有隔离且完美包装的CdI_4〜（2-）四面体，显示出中等的二次谐波（SHG），大约是KDP的三倍。

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《Inorganic Chemistry Communications》 |2004年第1期|共3页
作者
Peng Ren; Jingui Qin; Tao Liu; Shiwei Zhang;
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正文语种 eng
中图分类无机化学;
关键词
hybrid; synthesis; structure; second harmonic generation;

机译：混合;合成;结构;二次谐波产生;

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1. Synthesis,structure and second harmonic generation of novel inorganic-organic hybrid,(p-cyano-1-hydrogenpyridinium)_2CdI_4 [J] . Peng Ren, Jingui Qin, Tao Liu, Inorganic Chemistry Communications . 2004,第1期

机译：新型无机-有机杂化物（对氰基-1-氢吡啶鎓）_2CdI_4的合成，结构与二次谐波生成
2. Polyfunctional Inorganic-Organic Hybrid Materials: An Unusual Kind of NLO Active Layered Mixed Metal Oxalates with Tunable Magnetic Properties and Very Large Second Harmonic Generation [J] . Elena Cariati, Roberto Macchi, Dominique Roberto, Journal of the American Chemical Society . 2007,第30期

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Synthesis,structure and second harmonic generation of novel inorganic-organic hybrid,(p-cyano-1-hydrogenpyridinium)_2CdI_4

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