Synthesis and structure of [Mo_2O_4(acac)_2thala] centre dot 3C_2H_5OH with thala = 3-(2-thienyl)-DL-alanine as a third bridging ligand between two molybdenum atoms

Cindric Marina; Strukan Neven

首页> 外文期刊>Inorganic Chemistry Communications >Synthesis and structure of [Mo_2O_4(acac)_2thala] centre dot 3C_2H_5OH with thala = 3-(2-thienyl)-DL-alanine as a third bridging ligand between two molybdenum atoms

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Synthesis and structure of [Mo_2O_4(acac)_2thala] centre dot 3C_2H_5OH with thala = 3-(2-thienyl)-DL-alanine as a third bridging ligand between two molybdenum atoms

机译：[Mo_2O_4（acac）_2thala]中心点3C_2H_5OH的合成和结构，thala = 3-（2-噻吩基）-DL-丙氨酸作为两个钼原子之间的第三桥联配体

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As part of our study on oximolybdenum(V) complexes we present here here the synthesis and crystal structure of a novel dimeric oxomolybdate (V( [Mo_2O_4(acac)_2thala] centre dot 3C_2H_5OH (acac = acetylacetonate,thala = 3-(2-thienyl)-DL-alanine) in which two molybdenum atoms are being bridged not only by two oxo-oxygens but additionally by the amino acid carboxylate groups. Two octahedrally coordinated molybdenum atoms are singly bonded to each other at a distance of 2.5631 (5) A.

机译：作为我们对oximolybdenum（V）配合物的研究的一部分，我们在这里介绍新型二聚氧代钼酸盐（V（[Mo_2O_4（acac）_2thala]中心点3C_2H_5OH（acac =乙酰丙酮酸酯，thara = 3-（2- （噻吩基）-DL-丙氨酸），其中两个钼原子不仅被两个氧-氧桥连，而且还被氨基酸羧酸酯基桥接，两个八面体配位的钼原子以2.5631的距离相互键接（5）一种。

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《Inorganic Chemistry Communications》 |2000年第0期|共4页
作者
Cindric Marina; Strukan Neven;
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正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
Crystal structures; Molybdenum complexes; Oxo complexes; Amino acid complexes;

机译：晶体结构;钼配合物;氧配合物;氨基酸配合物;

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Synthesis and structure of [Mo_2O_4(acac)_2thala] centre dot 3C_2H_5OH with thala = 3-(2-thienyl)-DL-alanine as a third bridging ligand between two molybdenum atoms

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