Unusually high porosity in polymeric cluster cyanides:the synthesis and crystal structure of (H_3O)Zn_3[Re_6Se_8(CN)_6]_2·20H_2O

Naumov Nikolai G.; Virovets Alexander V.

首页> 外文期刊>Inorganic Chemistry Communications >Unusually high porosity in polymeric cluster cyanides:the synthesis and crystal structure of (H_3O)Zn_3[Re_6Se_8(CN)_6]_2·20H_2O

【24h】

Unusually high porosity in polymeric cluster cyanides:the synthesis and crystal structure of (H_3O)Zn_3[Re_6Se_8(CN)_6]_2·20H_2O

机译：聚合物簇状氰化物中异常高的孔隙度：（H_3O）Zn_3 [Re_6Se_8（CN）_6] _2·20H_2O的合成和晶体结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Mixing of aqueous solutions of the cluster anion[Re_6Se_8(CN)_6]~(4-) and Zn~(2+) in the presence of acetic acid(pH_3) leads to precipitation of(H_3O)_2Zn_3[Re_6Se_8(CN)_6]_2·20H_2O having a three dimensional framework of {Zn_3[Re_6Se_8(CN)_6}~(2-) formedby Re-C≡N-Zn covalent interactions.This framework occupies only 41.9% of the nuit cell volume.The rest of the space is filled by disordered water molecules and hydroxonium cations.

机译：团簇阴离子[Re_6Se_8（CN）_6]〜（4-）和Zn〜（2+）的水溶液在乙酸（pH_3）存在下的混合导致（H_3O）_2Zn_3 [Re_6Se_8（CN）_6）的沉淀] _2·20H_2O具有通过Re-C≡N-Zn共价相互作用形成的{Zn_3 [Re_6Se_8（CN）_6}〜（2-）三维构架，该构架仅占nuit细胞体积的41.9％。该空间充满了无序的水分子和氢氧鎓阳离子。

著录项

来源
《Inorganic Chemistry Communications》 |2000年第0期|共2页
作者
Naumov Nikolai G.; Virovets Alexander V.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
Crystal structures; Cluster compounds; Rhenium complexes; Cyanide complexes4aPorosity; Polymers;

机译：晶体结构;团簇化合物;hen配合物;氰化物配合物4a孔隙率;聚合物;

相似文献

外文文献
中文文献
专利

1. Unusually high porosity in polymeric cluster cyanides:the synthesis and crystal structure of (H_3O)Zn_3[Re_6Se_8(CN)_6]_2·20H_2O [J] . Naumov Nikolai G., Virovets Alexander V. Inorganic Chemistry Communications . 2000,第0期

机译：聚合物簇状氰化物中异常高的孔隙度：（H_3O）Zn_3 [Re_6Se_8（CN）_6] _2·20H_2O的合成和晶体结构
2. Novel cyanide-bridged three-dimensional coordination polymer derived from an octahedral rhenium cluster [Re6Te8(CN)(6)](4-): Synthesis and crystal structure of [{Mn(H2O)(2)(DMF)}(2)Re6Te8(CN)(6)]center dot 2H(2)O [J] . Mironov YV, Solodovnikov SF, Fedorov VE, Journal of structural chemistry . 2004,第5期

机译：衍生自八面体铼簇的新型氰化物桥接三维配位聚合物[Re6Te8（CN）（6）]（4-）：[{Mn（H 2 O）（2）（2）（DMF）}（2）的合成和晶体结构 Re6te8（CN）（6）]中心点2H（2）o
3. New Rhenium Octahedral Cluster Sulfido-cyanide Chain Polymer:The Synthesis and Crystal Structure of Cs_4[{Re_6S_8}(CN)_4S_(2/2)] [J] . N.G.Naumov, S.-J.Kim, A.V.Virovets, Bulletin of the Korean Chemical Society . 2006,第5期

机译：新型hen八面体簇硫氰化物链聚合物：Cs_4 [{Re_6S_8}（CN）_4S_（2/2）]的合成及晶体结构
4. Synthesis and Crystalline Structures of Cluster Co3(CO)7(μ3-S)μ, η 2-C*N*P (S) (C6H4OCH3)OC (Ph) (CH and Co3 (CO)7 (μ-S)μ, η2-S*CN*C(CH)P(S)(Cl)N(Ph) [C] . Min Guan 11th International Symposium of Fine Chemistry and Functional Polymers Jul 28-31, 2001 Hailar, Inner Mongolia, P.R. China . 2001

机译：团簇Co3（CO）7（μ3-S）μ，η2-C * N * P（S）（C6H4OCH3）OC（Ph）（CH）和Co3（CO）7（μ-S）的合成和晶体结构）μ，η2-S* CN * C（CH）P（S）（Cl）N（Ph）
5. AFM studies on detailed structures and dynamic growth of crystals in BA-Cn polymer films. [D] . Wang, Yong. 2006

机译：AFM研究BA-Cn聚合物薄膜中晶体的详细结构和动态生长。
6. Various Structural Types of Cyanide-Bridged FeIII–MnIII Bimetallic Coordination Polymers (CPs) and Polynuclear Clusters Based-on A New mer-Tricyanoiron(III)Building Block: Synthesis Crystal Structures and Magnetic Properties [O] . Wenlong Lan, Xiaoyun Hao, Yong Dou, 2019

机译：基于新的三氰基铁（III）构建基的氰化桥联的FeIII-MnIII双金属配位聚合物（CP）和多核簇的各种结构类型：合成晶体结构和磁性
7. Various Structural Types of Cyanide-Bridged FeIII–MnIII Bimetallic Coordination Polymers (CPs) and Polynuclear Clusters Based-on A New mer-Tricyanoiron(III)Building Block: Synthesis, Crystal Structures, and Magnetic Properties [O] . Wenlong Lan, Xiaoyun Hao, Yong Dou, 2019

机译：氰化物桥接的FeiII-MnIII双金属配位（CPS）和基于新的MER-TricyAnoIron（III）构建块：合成，晶体结构和磁性特性的各种结构类型
8. Crystal Structures of Hydrogen Cyanide, HCN. [R] . Dulmage, W. J., Lipscomb, W. N. 1951

机译：氰化氢，HCN的晶体结构。

Unusually high porosity in polymeric cluster cyanides:the synthesis and crystal structure of (H_3O)Zn_3[Re_6Se_8(CN)_6]_2·20H_2O

摘要

著录项

相似文献

相关主题

期刊订阅