Uranyl pyridine-dicarboxylate compounds with clustered water molecules

Yu-Sheng Jiang; Guang-Hua Li; Ye Tian; Zuo-Lei Liao; Jie-Sheng Chen

首页> 外文期刊>Inorganic Chemistry Communications >Uranyl pyridine-dicarboxylate compounds with clustered water molecules

【24h】

Uranyl pyridine-dicarboxylate compounds with clustered water molecules

机译：具有簇状水分子的铀酰吡啶-二羧酸酯化合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Two uranyl-containing organic coordination polymers,(UO_2)_2(mu_2-OH)(pdc)_2 Zn(bpy)(Ac)_2(H_2O)9 (1) (H_2pdc=pyridine-2,6-dicar-boxylic acid,bpy=4,4'-bipyridine,HAc=acetic acid) and UO_2(pdc)(H_2O) (2) have been prepared through a hydrothermal route and characterized by single-crystal X-ray diffraction,thermogravimetric analyses (TGA) and adsorption measurement 1 possesses infinite water cluster chains,which play an important role in the stabilization of the crystal structure.Whereas compound 2 is thermally stable up to at least 350 deg C,this material exhibits considerable adsorption capacity for water and methanol upon removal of the guest species in the microporous channels.

机译：（UO_2）_2（mu_2-OH）（pdc）_2 Zn（bpy）（Ac）_2（H_2O）9（1）（H_2pdc = pyridine-2,6-dicar-boxylic acid，通过水热法制备了bpy = 4,4'-联吡啶，HAc =乙酸）和UO_2（pdc）（H_2O）（2），并通过单晶X射线衍射，热重分析（TGA）和吸附进行了表征量具1拥有无限的水簇链，在稳定晶体结构中起着重要作用。而化合物2在至少350摄氏度的温度下仍具有热稳定性，该物质在去除客体后对水和甲醇具有相当大的吸附能力种在微孔通道中。

著录项

来源
《Inorganic Chemistry Communications》 |2006年第6期|共4页
作者
Yu-Sheng Jiang; Guang-Hua Li; Ye Tian; Zuo-Lei Liao; Jie-Sheng Chen;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Crystal structure; Water chain; Adsorption; Uranyl compounds;

机译：晶体结构;水链;吸附;铀酰化合物;

相似文献

外文文献
中文文献
专利

1. Uranyl pyridine-dicarboxylate compounds with clustered water molecules [J] . Yu-Sheng Jiang, Guang-Hua Li, Ye Tian, Inorganic Chemistry Communications . 2006,第6期

机译：具有簇状水分子的铀酰吡啶-二羧酸酯化合物
2. Role of Water in Photoreduction of Uranyl Ion. Disturbance of the Acid-Base Balance of Solution in Deactivation of Electronically Excited States of Uranyl Sulfate with Water Molecules [J] . N. G. Gorshkov, I. N. Izosimov, V. A. Mikhalev, Radiochemistry . 2011,第2期

机译：水在铀酰离子光还原中的作用。水分子使硫酸铀酰的电子激发态失活时溶液的酸碱平衡紊乱
3. A study of non-iterative triples contributions in relativistic equation-of-motion coupled-cluster calculations using an exact two-component Hamiltonian with atomic mean-field spin-orbit integrals: Application to uranyl and other heavy-element compounds [J] . Cheng Lan The Journal of Chemical Physics . 2019,第10期

机译：使用具有原子平均扫描轨道积分的精确双组分Hamiltonian的相对论式运动耦合簇计算中的非迭代性三元组贡献的研究：亚烷基和其他重核化合物的应用
4. Study on the Coordination of Amidoxime Small Molecule Ligands with Uranyl Ions Under Seawater Conditions [C] . Tingting Liu, Suliang Yang, Qian Liu, International Nuclear Fuel Cycle Conference . 2019

机译：海水条件下亚烷离子与亚烷离子的配位研究
5. Gas-phase ion-molecule clustering reactions of compounds involving two-center three-electron sulfur-sulfur bonds. [D] . James, Mary Allison. 1996

机译：涉及两中心三电子硫-硫键的化合物的气相离子分子簇反应。
6. The Evolution of Total Phenolic Compounds and Antioxidant Activities during Ripening of Grapes (Vitis vinifera L. cv. Tempranillo) Grown in Semiarid Region: Effects of Cluster Thinning and Water Deficit [O] . Inmaculada Garrido, David Uriarte, Marcos Hernández, 2016

机译：半干旱地区生长的葡萄（Vitis vinifera L.cv。Tempranillo）成熟过程中总酚类化合物的演变和抗氧化活性：疏果和水分亏缺的影响
7. Renormalized Coupled Cluster Approaches in the Cluster-in-Molecule Framework: Predicting Vertical Electron Binding Energies of the Anionic Water Clusters (H2O)n– [O] . Peng Xu, Mark S. Gordon 2014

机译：在分子集聚框架中的重新定位耦合簇接近：预测阴离子水簇的垂直电子结合能量（H2O）n-
8. A Computer Simulation Method for the Calculation of Equilibrium Constants for the Formation of Physical Clusters of Molecules: Application to Small Water Clusters [R] . Swope, W. C., Andersen, H. C., Berens, P. H., 1981

机译：计算分子物理团簇平衡常数的计算机模拟方法：小水团簇的应用

Uranyl pyridine-dicarboxylate compounds with clustered water molecules

摘要

著录项

相似文献

相关主题

期刊订阅