Experimental and theoretical study on a novel supramolecular complex constructed from benzenetetracarboxylatic acid and 1,2,3,4-tetra(4-pyridlyl)thiophene

Ling Qiu; Wenxin Li; Xiaowei Fan

首页> 外文期刊>Inorganic Chemistry Communications >Experimental and theoretical study on a novel supramolecular complex constructed from benzenetetracarboxylatic acid and 1,2,3,4-tetra(4-pyridlyl)thiophene

【24h】

Experimental and theoretical study on a novel supramolecular complex constructed from benzenetetracarboxylatic acid and 1,2,3,4-tetra(4-pyridlyl)thiophene

机译：由苯四甲酸和1,2,3,4-四（4-吡啶基）噻吩构成的新型超分子配合物的实验和理论研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Hydrothermal reaction of benzenetetracarboxylatic acid (H4BTC) with l,2,3,4-tetra(4-pyridlyl)thiophene (TPT) afforded a novel supramolecular complex [(H4BTC))(TPT)]_n (1),which was characterized by FT-IR spectroscopy,elemental analysis,luminescence and thermogravimetric analysis.X-ray single-crystal diffraction reveals that 1 exhibits a one-dimensional (1-D) wave-shape chain assembled through strong hydrogen bonds.Density functional theory (DFT) calculations show that the optimized structures closely resemble the experimental structures.The electronic absorption spectrum of the model dimer in its singlet state has been studied by a time-dependent DFT (TD-DFT) calculation and the nature of the molecular orbitals involved in the fluorescent property was verified.

机译：苯四甲酸（H4BTC）与1,2,3,4-四（4-吡啶基）噻吩（TPT）的水热反应可制得新型的超分子络合物[（H4BTC））（TPT）] _ n（1） FT-IR光谱，元素分析，发光和热重分析。X射线单晶衍射显示1具有通过强氢键组装的一维（1-D）波形链。密度泛函理论（DFT）计算结果表明优化后的结构与实验结构非常相似。通过时间依赖的DFT（TD-DFT）计算以及荧光性质所涉及的分子轨道的性质，研究了模型二聚体处于单峰态的电子吸收光谱。已验证。

著录项

来源
《Inorganic Chemistry Communications》 |2008年第7期|共3页
作者
Ling Qiu; Wenxin Li; Xiaowei Fan;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Supramolecular complex; Crystal structure; Fluorescent spectrum; DFT and TD-DFT calculation;

机译：超分子配合物;晶体结构;荧光光谱;DFT和TD-DFT计算;

相似文献

外文文献
中文文献
专利

1. Experimental and theoretical study on a novel supramolecular complex constructed from benzenetetracarboxylatic acid and 1,2,3,4-tetra(4-pyridlyl)thiophene [J] . Ling Qiu, Wenxin Li, Xiaowei Fan Inorganic Chemistry Communications . 2008,第7期

机译：由苯四甲酸和1,2,3,4-四（4-吡啶基）噻吩构成的新型超分子配合物的实验和理论研究
2. 1,2,3,4-tetrahydroquinoline-based selective human neuronal nitric oxide synthase (nNOS) inhibitors: Lead optimization studies resulting in the identification of N-(1-(2-(methylamino)ethyl)-1,2,3,4-tetrahydroquinolin-6-yl) thiophene-2-carboximidamide as a preclinical development candidate [J] . Ramnauth J., Renton P., Dove P., Journal of Medicinal Chemistry . 2012,第6期

机译：1,2,3,4-基于四氢喹啉的选择性人神经元一氧化氮合酶（nNOS）抑制剂：铅优化研究导致鉴定出N-（1-（2-（甲基氨基）乙基）-1,2,3， 4-四氢喹啉-6-基）噻吩-2-羧酰亚胺酰胺作为临床前开发候选药物
3. Theoretical studies on vicinal-tetrazine compounds: furoxano-1,2,3,4-tetrazine-1,3,5-trioxide (FTTO-alpha) and furoxano-1,2,3,4-tetrazine-1,3,7-trioxide (FTTO-beta) [J] . Wang Tianyi, Zhang Tao, Xu Liwen, Journal of molecular modeling . 2014,第12期

机译：邻四嗪化合物的理论研究：呋喃并-1,2,3,4-四嗪-1,3,5-三氧化物（FTTO-alpha）和呋喃并-1,2,3,4-四嗪-1,3,7 -三氧化物（FTTO-beta）
4. Supramolecular Complexes of Humic Acids Including Complexation of Nano-particles. Spectrophotometric, Spectrofluorimetric, Capillary Electrophoretic and Mass Spectrometric Study [C] . Josef Havel, Eladia M. Pena-Mendez International Meeting of the International Humic Substances Society . 2010

机译：腐殖酸的超分子复合物，包括纳米颗粒的络合。分光光度法，光谱氟化，毛细管电泳和质谱研究
5. Dual labeled TIPP (Tyr-Tic-Phe-Phe, Tic = 1,2,3,4-tetrahydroisoquinoline-3-carboxylic acid) peptides as pharmacological tools to study delta opioid receptors [D] . Peck, Angela Marie 2007

机译：双标记的TIPP（Tyr-Tic-Phe-Phe，Tic = 1,2,3,4-四氢异喹啉3-羧酸）肽作为研究δ阿片受体的药理学工具
6. Experimental and Theoretical Aspects of Anion Complexes with a Thiophene-Based Cryptand [O] . Syed A. Haque, Musabbir A. Saeed, Afsana Jahan, -1

机译：带有噻吩基墓穴的阴离子配合物的实验和理论方面
7. Effects of N-oxidation on the molecular and crystal structures and properties of isocinchomeronic acid, its metal complexes and their supramolecular architectures: experimental, CSD survey, solution and theoretical approaches [O] . Zahra Hosseini-Hashemi, Masoud Mirzaei, Ameneh Jafari, 2019

机译：n-氧化对异链酸，其金属络合物及其超分子架构的分子和晶体结构及性能的影响：实验，CSD调查，解决方案和理论方法
8. Interaction Between Aromatic Hydrocarbons and Ansolvo-Acids. IV. The Uv Absorption Spectra of the Aromatic/AlCl sub 3 Complexes in a Solid State (1,2-Benzopentacene, Triphenylene, 1,2,3,4-Dibenzotetracene, 1,2,8,9-Dibenzopentacene [R] . Perkampus, H. H., Kranz, T. 1963

机译：芳烃与安索沃酸的相互作用。 IV。固态芳香族/ alCl亚3配合物的紫外吸收光谱（1,2-苯并戊炔，三亚苯基，1,2,3,4-二苯并四苯，1,2,8,9-二苯并并五苯

Experimental and theoretical study on a novel supramolecular complex constructed from benzenetetracarboxylatic acid and 1,2,3,4-tetra(4-pyridlyl)thiophene

摘要

著录项

相似文献

相关主题

期刊订阅