Solvent-induced two heterometallic coordination polymers based on a flexible ferrocenyl ligand

Chun-Yan Cao; Kai-Ju Wei; Jia Ni

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Solvent-induced two heterometallic coordination polymers based on a flexible ferrocenyl ligand

机译：溶剂诱导的基于柔性二茂铁基配体的两种杂金属配位聚合物

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The bidentate ferrocenyl sandwich molecule N,N'-bis-3-pyridylmethyl-1,1'-ferrocenedicarboxamide (3-BPMFA) has been employed as an organometallic coordination ligand in reaction with CdBr2 to construct heterobimetallic architectures. By assembling the flexible arm-like molecule with CdBr2, two novel bimetallic 1D chain structures are constructed in different solvent systems: the solvated [Cd(μ-3-BPMFA)2Br2]_n·nMeOH (1) from methanol and the unsolvated [Cd(3-BPMFA)(μ-Br)2]_n (2) from DMF-Et2O. Different roles of bromine ions have been observed in these two complexes. In 1, bromine ions only act as terminal coordinated ligand, while they play bridging roles in 2. Electrochemistry properties of the ligand and complexes were discussed preliminarily.

机译：二齿二茂铁基夹心分子N，N′-双-3-吡啶基甲基-1，1′-二茂铁二甲酰胺（3-BPMFA）已被用作与CdBr2反应的有机金属配位体，以构建异双金属结构。通过将柔性臂状分子与CdBr2组装在一起，在不同的溶剂系统中构造了两个新颖的双金属一维链结构：由甲醇形成的溶剂化[Cd（μ-3-BPMFA）2Br2] _n·nMeOH（1）和未溶解的[Cd （3-BPMFA）（μ-Br）2] _n（2）来自DMF-Et2O。在这两种络合物中已观察到溴离子的不同作用。在1中，溴离子仅充当末端配位配体，而在2中起桥联作用。初步讨论了该配体和配合物的电化学性质。

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《Inorganic Chemistry Communications》 |2010年第1期|共3页
作者
Chun-Yan Cao; Kai-Ju Wei; Jia Ni;
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正文语种 eng
中图分类无机化学;
关键词
Ferrocene; Coordination polymer; Cd complex; Electrochemical properties;

机译：二茂铁;配位聚合物;Cd配合物;电化学性能;

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专利

1. Solvent-induced two heterometallic coordination polymers based on a flexible ferrocenyl ligand [J] . Chun-Yan Cao, Kai-Ju Wei, Jia Ni Inorganic Chemistry Communications . 2010,第1期

机译：溶剂诱导的基于柔性二茂铁基配体的两种杂金属配位聚合物
2. Solvent-induced synthesis of cobalt(II) coordination polymers based on a rigid ligand and flexible carboxylic acid ligands: syntheses, structures and magnetic properties [J] . Wang Ting, Zhang Chuanlei, Ju Zemin, Dalton transactions: An international journal of inorganic chemistry . 2015,第15期

机译：溶剂诱导的基于刚性配体和柔性羧酸配体的钴（II）配位聚合物的合成：合成，结构和磁性
3. Three new 3-D inorganic-organic coordination polymers constructed from polyoxovanadate-based heterometallic network and flexible bis(imidazole) ligand: Syntheses, structures and properties [J] . Wang XL, Chen BK, Liu GC, Journal of Organometallic Chemistry . 2010,第6期

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4. Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer Co_3(bpd)_(5.5)(NCS)_6(NH_3)_n·2H_2O (bpd= 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene) [C] . Yuqi Liu, Yong Yang, Rui Yang, International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials . 2013

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5. Syntheses and characterization of homo- and heterometallic tert-butoxides/cyclopentadienides of group 4/14 metals and mixed ligand (tert-butoxides/cyclopentadienides) coordination polymers of group 1/14 metals [D] . Njua, Edmond Yong 2012

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6. Four Novel Zn (II) Coordination Polymers Based on 4′-Ferrocenyl-32′:6′3′′-Terpyridine: Engineering a Switch from 1D Helical Polymer Chain to 2D Network by Coordination Anion Modulation [O] . Lufei Xiao, Dajun Wu, Xuchun Wang, 2017

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机译：Cyanido-Bridged异金属寡核配合物和配位聚合物使用三齿希夫碱配体构建：合成，晶体结构，磁性和发光性质。一种新的三聚体水簇

Solvent-induced two heterometallic coordination polymers based on a flexible ferrocenyl ligand

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