A luminescent Cu(I) complex ligated by 1,3-bis(4-pyridyl)trisulfane generated in situ by the coupling of pyridine-4-thiol

Jian Zhang; Jian-Kai Cheng; Ye-Yan Qin

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A luminescent Cu(I) complex ligated by 1,3-bis(4-pyridyl)trisulfane generated in situ by the coupling of pyridine-4-thiol

机译：发光的Cu（I）配合物，通过吡啶-4-硫醇的偶联反应原位生成1,3-双（4-吡啶基）三硫烷

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摘要

A luminescent Cu(I) complex was synthesized via a series of processes under solvothermal condition. It is the first example of a clear transformation from pyridine-4-thiol to a polysulfide compound 1,3-bis(4-pyridyl)trisulfane.

机译：通过溶剂热条件下的一系列过程合成了发光的Cu（I）配合物。这是从吡啶-4-硫醇到多硫化物化合物1,3-双（4-吡啶基）三硫烷的清晰转化的第一个例子。

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《Inorganic Chemistry Communications》 |2008年第2期|共3页
作者
Jian Zhang; Jian-Kai Cheng; Ye-Yan Qin;
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正文语种 eng
中图分类无机化学;
关键词
Polysulfide; Solvothermal synthesis; Pyridine-4-thiol; Luminescence; Copper(I);

机译：多硫化物;溶剂热合成;吡啶-4-硫醇;发光;铜（I）;

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1. A luminescent Cu(I) complex ligated by 1,3-bis(4-pyridyl)trisulfane generated in situ by the coupling of pyridine-4-thiol [J] . Jian Zhang, Jian-Kai Cheng, Ye-Yan Qin Inorganic Chemistry Communications . 2008,第2期

机译：发光的Cu（I）配合物，通过吡啶-4-硫醇的偶联反应原位生成1,3-双（4-吡啶基）三硫烷
2. Syntheses, Structural Characterization, and Properties of {[Cu(bpp)_2(H_2O)_2](tp) ? 7H_2O} and {[Cu(bpp)_2(H_2O)](ip) ? 7H_2O} Complexes. New Examples of the Organic Anionic Template Effect on Induced Assembly of Water Clusters (bpp = 1,3-Bis(4-pyridyl)propane, tp = Terephthalate, ip = Isophthalate) [J] . Luo Geng-Geng, Xiong Hong-Bo, Dai Jing-Cao Crystal growth & design . 2011,第2期

机译：{[Cu（bpp）_2（H_2O）_2]（tp）？的合成，结构表征和性质7H_2O}和{[Cu（bpp）_2（H_2O）]（ip）吗？ 7H_2O}复合物。有机阴离子模板对水簇诱导组装的新实例（bpp = 1,3-双（4-吡啶基）丙烷，tp =对苯二甲酸酯，ip =间苯二甲酸酯）
3. Synthesis of mono- and bis-tetrazolato complexes of Ni(II), Pt(II) and Cu(II) via 1,3-dipolar cycloadditions of 2-cyanopyridines with metal ligated azides in N,N,O-aminoiminophenolato complexes [J] . Mukhopadhyay BG, Mukhopadhyay S, da Silva MFCG, Dalton transactions: An international journal of inorganic chemistry . 2009,第24期

机译：在N，N，O-氨基亚氨基酚络合物中，通过2-氰基吡啶与金属连接的叠氮化物的1,3-偶极环加成反应合成Ni（II），Pt（II）和Cu（II）的单和双四唑酸酯络合物
4. Spin state of mixed crystals of iron with zinc or cobalt for the assembled complexes bridged by 1,3-bis(4-pyridyl)propanes [C] . S Nakashima, T Dote, M Atsuchi, International conference on applications of the mossbauer effect;ICAME 2009 . 2009

机译：铁与锌或钴的混合晶体的自旋态，用于由1,3-双（4-吡啶基）丙烷桥接的组装配合物
5. Phosgene-Free Synthesis of Verdazyl Radicals and Enantioselective 1,3-Dipolar Cycloaddition Reactions of Azomethine Imines Generated in situ from Verdazyl Radicals. [D] . Youn, Beom. 2012

机译：Verdazyl自由基的无光合成方法和Verdazyl自由基就地生成的偶氮甲亚胺的对映选择性1,3-偶极环加成反应。
6. Generating Cu(II)-Oxyl / Cu(III)-Oxo Species from Cu(I)-α-Ketocarboxylate Complexes and O2: In silico Studies on Ligand Effects and C-H-activation Reactivity [O] . Dr. Stefan M. Huber, M. Zahid Ertem, Dr. Francesco Aquilante, -1

机译：从Cu（I）-α-酮羧酸酯配合物和O2生成Cu（II）-Oxyl / Cu（III）-Oxo物种：配体效应和C-H活化反应性的计算机模拟研究
7. Copper(II) Complexes of 2-Amino-2-hydroxymethyl-1,3-propanediol. Part 4. Synthesis, Structure and Thermal Behavior of trans-Bis2-amino-2-hydroxymethyl-1,3-propanediolato-O,Ncopper(II) Potassium Fluoride and Bromide, Cu(C4H10NO3)2KF.3H2O and Cu(C4H10NO3)2KBr.2H2O. [O] . Sirpa Kotila, Jussi Valkonen, Elias D. Kouvelas, 1994

机译：2-氨基-2-羟甲基-1,3-丙二醇的铜（II）复合物。第4部分反式双2-氨基-2-羟甲基-1,3-丙二醇-O，N氟化钾和溴化钾的合成，结构和热行为，Cu（C4H10NO3）2 Kf。 3H2O和Cu（C4H10NO3）2 KBR.2H2O。
8. Binuclear Schiff Base Complexes of m-Xylylenebis(2-(1,3-Propanedi (2-Pyridinealdimine)) and M-Xylylenebis(2-(1,3-Propanedi(2-Pyrrolealdimine) [R] . Whitmore, B. C., Eisenberg, R. 1983

机译：间二甲苯胺schiff碱配合物的间苯二甲基双（2-（1,3-丙二胺（2-吡啶二胺））和m-二甲苯二（2-（1,3-丙二醛）（2-吡咯醛））

A luminescent Cu(I) complex ligated by 1,3-bis(4-pyridyl)trisulfane generated in situ by the coupling of pyridine-4-thiol

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