Synthesis and characterization of a mixed-valence hexadecavanadate cluster with half-open framework

Lian Chen; Fei-Long Jiang; Ning Li

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Synthesis and characterization of a mixed-valence hexadecavanadate cluster with half-open framework

机译：具有半开放骨架的混合价十六烷酸酯簇的合成与表征

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A new mixed-valence hexadecavanadate cluster compound, (Me2NH2)4[H6V_(16)O_(42)(SO4)]·8H2O (1), has been synthesized via an efficient method in organic media. The hollow cluster shell of 1, with a sulfate ion locating in its centre, exhibits four large eight-membered -O-V-O-V- rings on its surface, which makes the cluster into a half-open structure distinguished from the common hollow clusters built up with closed surfaces. The intense blue luminescence of 1 in solution state is scarcely reported for the polyoxometaiate clusters.

机译：通过有机介质中的有效方法合成了一种新的混合价十六烷酸簇簇化合物（Me2NH2）4 [H6V_（16）O_（42）（SO4）]·8H2O（1）。 1的空心簇状壳的中心有硫酸根离子，在其表面上有四个大的八元-OVOV-环，这使该簇成为半开结构，这与封闭的普通空心簇不同表面。几乎没有报道聚氧肟酸酯簇在溶液状态下呈1的强烈蓝色发光。

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《Inorganic Chemistry Communications》 |2009年第3期|共4页
作者
Lian Chen; Fei-Long Jiang; Ning Li;
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正文语种 eng
中图分类无机化学;
关键词
Vanadium; Hexadecavanadate; Polyoxometaiate; Cluster structure;

机译：钒;十六烷基钒酸盐;多甲酸酯;簇结构;

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专利

1. Synthesis and characterization of a mixed-valence hexadecavanadate cluster with half-open framework [J] . Lian Chen, Fei-Long Jiang, Ning Li Inorganic Chemistry Communications . 2009,第3期

机译：具有半开放骨架的混合价十六烷酸酯簇的合成与表征
2. Synthesis and characterization of a mixed-valence hexadecavanadate cluster with half-open framework [J] . Lian Chen, Fei-Long Jiang, Ning Li Inorganic Chemistry Communications . 2009,第3期

机译：具有半开放骨架的混合价十六烷酸酯簇的合成与表征
3. The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis,structure an characterization of[V_(16)O_(38)(Cl)]~(8-) [J] . Yanhui Chen, Xiaojun Gu, Jun peng, Inorganic Chemistry Communications . 2004,第5期

机译：第一个离散的混合价十六烷钒酸酯主体壳簇阴离子：水热合成，结构表征[V_（16）O_（38）（Cl）]〜（8-）
4. Synthesis, Crystal Structure and Characterizations of a Novel Open-framework Lanthanide Imidazoledicarboxylate [C] . Hui-duan Li International Conference on Advances in Materials . 2015

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Synthesis and characterization of a mixed-valence hexadecavanadate cluster with half-open framework

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