The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis,structure an characterization of[V_(16)O_(38)(Cl)]~(8-)

Yanhui Chen; Xiaojun Gu; Jun peng; Zheny Shi; Hongquan Yu; Enbo Wang; Ninghai Hu

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The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis,structure an characterization of[V_(16)O_(38)(Cl)]~(8-)

机译：第一个离散的混合价十六烷钒酸酯主体壳簇阴离子：水热合成，结构表征[V_（16）O_（38）（Cl）]〜（8-）

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A new compound,[NH_4]_2[Zn(phen)_3]_2[Zn(phen)_2(H_2O)_2][V_(16)O_(38)(Cl)](center dot)5H_2O(1),was synthesized in the hydrothermal condition. The "naked"[V_(16)O_(38)(Cl)]~(8-) is the first observation with host shell structure in polyoxovanadate chemistry.Over the past years,polyoxometalate received extensive attention due to their structure diversity and potential applications in many areas such as catalysis,analytical chemistry,nanotechnology,chemical sensing,biochemical and geochemical processes,medicine and materials science [1-3].

机译：得到了一种新化合物[NH_4] _2 [Zn（phen）_3] _2 [Zn（phen）_2（H_2O）_2] [V_（16）O_（38）（Cl）]（中心点）5H_2O（1）在水热条件下合成。 “裸” [V_（16）O_（38）（Cl）]〜（8-）是聚氧钒酸盐化学中具有宿主壳结构的第一个观察结果。近年来，多金属氧酸盐因其结构多样性和潜力而受到广泛关注。在催化，分析化学，纳米技术，化学传感，生化和地球化学过程，医学和材料科学等许多领域的应用[1-3]。

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来源
《Inorganic Chemistry Communications》 |2004年第5期|共3页
作者
Yanhui Chen; Xiaojun Gu; Jun peng; Zheny Shi; Hongquan Yu; Enbo Wang; Ninghai Hu;
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正文语种 eng
中图分类无机化学;
关键词
Hydrothermal synthesis; Crystal structure; Polyoxovanadate; Phen;

机译：水热合成;晶体结构;聚氧钒酸盐;苯;

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1. The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis,structure an characterization of[V_(16)O_(38)(Cl)]~(8-) [J] . Yanhui Chen, Xiaojun Gu, Jun peng, Inorganic Chemistry Communications . 2004,第5期

机译：第一个离散的混合价十六烷钒酸酯主体壳簇阴离子：水热合成，结构表征[V_（16）O_（38）（Cl）]〜（8-）
2. Hydrothermal Synthesis and Characterization of [V_(16)O_(38)(Cl)][Cu(enMe)_2]_(3.5) · 2H_2O Containing {V_(16)O_(38)} Cluster [J] . CUI Xiao-bing, ZHENG Shou-tian, SUN Yan-qiong, Chemical Research in Chinese Universities . 2004,第3期

机译：[V_（16）O_（38）（Cl）] [Cu（enMe）_2] _（3.5）·2H_2O含{V_（16）O_（38）}团簇的水热合成及表征
3. Hydrothermal syntheses and crystal structures of two new mixed-valence vanadium oxides [Ni(en)_2(H_2O)_2][Ni(en) _3]_2[V_(16)O_(38)Cl] · 3(H _2O) and (H_3O)_2V_3O_8 [J] . Liu X., Yin X.-H., Zhang F. Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2010,第12期

机译：两种新的混合价钒氧化物[Ni（en）_2（H_2O）_2] [Ni（en）_3] _2 [V_（16）O_（38）Cl]·3（H _2O）的水热合成和晶体结构（H_3O）_2V_3O_8
4. Hydrothermal Synthesis and Crystal Structure of a Novel Discrete Dodecanuclear62+ Iodocuprate(I) Cu10I16 - with Ni(phen)3 as a Template [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以Ni（phen）3为模板的新型离散十二碳六烯碘酸盐（I）Cu10I16-的水热合成和晶体结构
5. Octahedral metal clusters as molecular building blocks of coordination polymers: Synthesis, characterization, and study of their host-guest interactions. [D] . Chen, Lei. 2011

机译：八面体金属簇作为配位聚合物的分子构建基块：合成，表征和研究其主客体相互作用。
6. Methane activation by gold-doped titanium oxide cluster anions with closed-shell electronic structures [O] . Yan-Xia Zhao, Xiao-Na Li, Zhen Yuan, 2016

机译：闭壳电子结构的金掺杂二氧化钛簇阴离子对甲烷的活化
7. Unprecedented Connection Mode of [V16Sb4O42(H2O)]8- Cluster Anions by Mn2+ Centered Complexes: Solvothermal Synthesis and Properties of {[Mn(teta)]4V16Sb4O42(H2O}n·[(H2O)12]n [O] . Rasmussen, Maren, Näther, Christian, van Leusen, Jan, 2017

机译：[V16Sb4O42（H2O）] 8-簇阴离子与Mn2 +中心配合物的空前连接方式：{[Mn（teta）] 4V16Sb4O42（H2O} n·[（H2O）12] n的溶剂热合成及性能
8. Metal Atom Synthesis of Metallaboron Clusters. 8. Synthesis of New Cobalt, Iron, and Nickel Clusters Derived from 2,6-C2B7H11. Structural Characterization of 2-ETA 6-C6(CH3)3H3 Fe-1,6-C2B7H9, 6-ETA 6-C6(CH3)3H3 Fe-9,10-C2B7H11, and 5,7,8-(CH3)-11,7,8,10- ETA 3-C4(CH3)4H niC3B7H7. [R] . Sneddon, L. G., Briguglio, J. J. 1986

机译：metallaboron团簇的金属原子合成。 8.衍生自2,6-C2B7H11的新的钴，铁和镍簇的合成。 2-ETa 6-C6（CH3）3H3Fe-1,6-C2B7H9,6-ETa6-C6（CH3）3H3Fe-9,10-C2B7H11和5,7,8-（CH3）的结构表征 - 11,7,8,10- ETa 3-C4（CH3）4HiC3B7H7。

The first discrete mixed-valence hexadecavanadate host shell cluster anions: hydrothermal synthesis,structure an characterization of[V_(16)O_(38)(Cl)]~(8-)

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