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首页> 外文期刊>Inorganic Chemistry Communications >Three-dimensional porous metal-organic replica of natural mineral α-Al2O3 based on hexadentate triazine derivative
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Three-dimensional porous metal-organic replica of natural mineral α-Al2O3 based on hexadentate triazine derivative

机译：基于六齿三嗪衍生物的天然矿物α-Al2O3的三维多孔金属有机仿品

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摘要

A non-interpenetrated 3D porous metal-organic framework [(CH3)2NH2]2[Cd(TATAT)_(2/3)·4DMF (1) (TATAT = 5,5',5"-(1,3,5-triazine-2,4,6-triyl)tris(azanediyl)triisophthalate) has been successfully synthesized under solvothermal conditions and characterized by elemental analysis, TGA, and single-crystal X-ray diffraction analysis. Compound 1 exhibits α-Al2O3 (corundum) topology and represents the first metal-organic analog presently known with a natural material topology based on 6-connected organic ligand and tetrahedral metal ion. In addition, the thermal stabilities of the complex and the acid-treated product have been investigated and the results indicate that acid treatment is an efficient way for this compound to improve its thermal stability.
机译：非互穿的3D多孔金属有机骨架[（CH3）2NH2] 2 [Cd（TATAT）_（2/3）·4DMF（1）（TATAT = 5,5'，5“-（1,3,5溶剂热条件下成功合成了-（triazine-2,4,6-triyl）tris（azanediyl）triisophthalate），并通过元素分析，TGA和单晶X射线衍射分析对其进行了表征，化合物1表现出α-Al2O3（刚玉） ）拓扑结构，代表了目前已知的第一个金属-有机类似物，具有基于六连接有机配体和四面体金属离子的天然材料拓扑结构。此外，还研究了配合物和酸处理产物的热稳定性，并得出了结果表明酸处理是该化合物提高其热稳定性的有效方法。

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