Synthesis and structure of an unprecedented supramolecular bridged-hydroxyl manganese(III)-lithium(I) coordination polymer [Mn~(III)L(OH)2Li~I]_n through both intermolecular hydrogen bonds and π-π stacking interactions

Wen-Kui Dong; Chun-Yu Zhao; Yin-Xia Sun

首页> 外文期刊>Inorganic Chemistry Communications >Synthesis and structure of an unprecedented supramolecular bridged-hydroxyl manganese(III)-lithium(I) coordination polymer [Mn~(III)L(OH)2Li~I]_n through both intermolecular hydrogen bonds and π-π stacking interactions

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Synthesis and structure of an unprecedented supramolecular bridged-hydroxyl manganese(III)-lithium(I) coordination polymer [Mn~(III)L(OH)2Li~I]_n through both intermolecular hydrogen bonds and π-π stacking interactions

机译：通过分子间氢键和π-π堆积相互作用的空前超分子桥连式羟基锰（III）-锂（I）配位聚合物[Mn〜（III）L（OH）2Li〜I] _n的合成与结构

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摘要

An unprecedented linear supramolecular manganese(III)-lithium(I) coordination polymer, [Mn~(III)L(OH)2-Li~1]_n, has been prepared and structurally characterized. The polymer is a one-dimensional infinite Mn(III)-O-Li(I) chain supramolecular structure formed by intermolecular O-H···O and O-H···Cl hydrogen bonds and π -π stacking of neighboring benzene rings.

机译：制备了一种前所未有的线性超分子锰（III）-锂（I）配位聚合物[Mn〜（III）L（OH）2-Li〜1] _n，并对其结构进行了表征。该聚合物是一维无限大的Mn（III）-O-Li（I）链超分子结构，由分子间的O-H··O和O-H···Cl氢键和相邻苯环的π-π堆积形成。

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来源
《Inorganic Chemistry Communications》 |2009年第3期|共3页
作者
Wen-Kui Dong; Chun-Yu Zhao; Yin-Xia Sun;
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正文语种 eng
中图分类无机化学;
关键词
Salen-type bisoxime ligand; Mn(III) polymer; Synthesis; Supramolecular structure;

机译：Salen型双肟配体;Mn（III）聚合物;合成;超分子结构;

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1. Synthesis and structure of an unprecedented supramolecular bridged-hydroxyl manganese(III)-lithium(I) coordination polymer [Mn~(III)L(OH)2Li~I]_n through both intermolecular hydrogen bonds and π-π stacking interactions [J] . Wen-Kui Dong, Chun-Yu Zhao, Yin-Xia Sun Inorganic Chemistry Communications . 2009,第3期

机译：通过分子间氢键和π-π堆积相互作用的空前超分子桥连式羟基锰（III）-锂（I）配位聚合物[Mn〜（III）L（OH）2Li〜I] _n的合成与结构
2. One-pot synthesis of an Mn(III)-Cu(II)-Mn(III) trinuclear heterometallic compound formed by Mn...S-Cu-S...Mn supramolecular interactions:Crystal structure of [{Mn~(III)(salph)(H_2O)}_2{Cu~(II)(mnt)_2}] centre dot 4DMF [J] . VEDICHI MADHU, SAMAR K DAS Journal of chemical sciences . 2006,第6期

机译：一锅合成由Mn ... S-Cu-S ... Mn超分子相互作用形成的Mn（III）-Cu（II）-Mn（III）三核异金属化合物：[{Mn〜（III ）（salph）（H_2O）} _ 2 {Cu〜（II）（mnt）_2}]中心点4DMF
3. One-pot synthesis of an Mn(III)-Cu(II)-Mn(III) trinuclear heterometallic compound formed by Mn$cdots$S-Cu-S$cdots$Mn supramolecular interactions: Crystal structure of [{MnIII(salph)(H2O)}2{CuII(mnt)2}]$cdot$4DMF [J] . Samar K Das1, Vedichi Madhu Journal of Chemical Sciences . 2006,第6期

机译：一锅合成由Mn $ cdots $ S-Cu-S $ cdots $ Mn超分子相互作用形成的Mn（III）-Cu（II）-Mn（III）三核异金属化合物：[{MnIII（salph）的晶体结构（H2O）} 2 {CuII（mnt）2}] $ cdot $ 4DMF
4. Supramolecular Polymers Formed by Intermolecular Interaction of Hydrogen Bonding [C] . Taiho Park, Steven C. Zimmerman, Hugo C. Ong PMSE Symposia . 2007

机译：通过氢键的分子间相互作用形成的超分子聚合物
5. Synthesis, spectroscopic studies and structure of gold(III) chloride compounds of heterocyclic N-oxide diadducts revealing short hydrogen bond. [D] . Al-Hamoud, Saud A. Aziz. 1985

机译：杂环N-氧化物二加合物的金（III）氯化金化合物的合成，光谱研究和结构，揭示了短的氢键。
6. ‘Metal Complexes as Ligands’ for the Synthesis of Coordination Polymers: A MnIII Monomer as a Building Block for the Preparation of an Unprecedented 1-D {MnIIMnIII}n Linear Chain [O] . Konstantinos N. Pantelis, Georgios Karotsis, Christos Lampropoulos, 2020

机译：用于配位聚合物合成的金属配体配体：MnIII单体作为构建空前的1-D {MnIIMnIII} n线性链的基础
7. Role of Ethynyl-Derived Weak Hydrogen-Bond Interactions in the Supramolecular Structures of 1D, 2D, and 3D Coordination Polymers Containing 5-Ethynyl-1,3-benzenedicarboxylate [O] . Knichal Jane V., Gee William J., Burrows Andrew D., 2015

机译：乙炔基弱氢键相互作用在含5-乙炔基-1,3-苯二甲酸的1D，2D和3D配位聚合物的超分子结构中的作用

Synthesis and structure of an unprecedented supramolecular bridged-hydroxyl manganese(III)-lithium(I) coordination polymer [Mn~(III)L(OH)2Li~I]_n through both intermolecular hydrogen bonds and π-π stacking interactions

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