Self-assembly of a hydrated chiral C_2-symmetric bisferrocenylimine via C-H···pi and N···H-O-H···N interactions

Vamsee Krishna Muppidi; Tin Htwe; P.S.Zacharias; Samudranil Pal

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Self-assembly of a hydrated chiral C_2-symmetric bisferrocenylimine via C-H···pi and N···H-O-H···N interactions

机译：通过C-H···pi和N···H-O-H···N相互作用水合手性C_2-对称双二茂铁亚胺的自组装

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摘要

The crystal structure of (1R,2R)-bis(ferrocenylimine)cyclohexane reveals a helical structure due to self-assembling via C-H···pi interactions.Hydrogen bonds involving the water molecules present in the crystal lattice and additional C-H···pi interactions act as bridges between the parallel helices and a two-dimensional network is formed.

机译：（1R，2R）-双（二茂铁基亚胺）环己烷的晶体结构由于通过CH···pi相互作用而自组装而显示出螺旋结构。涉及晶格中存在的水分子和其他CH···pi的氢键相互作用充当平行螺旋之间的桥梁，并形成了二维网络。

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《Inorganic Chemistry Communications》 |2004年第9期|共4页
作者
Vamsee Krishna Muppidi; Tin Htwe; P.S.Zacharias; Samudranil Pal;
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原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Ferrocene; Schiff base; Chiral; Crystal structure; C-H···pi interaction; Helical;

机译：二茂铁;席夫碱;手性;晶体结构;C-H··pi相互作用;螺旋;

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1. Self-assembly of a hydrated chiral C_2-symmetric bisferrocenylimine via C-H···pi and N···H-O-H···N interactions [J] . Vamsee Krishna Muppidi, Tin Htwe, P.S.Zacharias, Inorganic Chemistry Communications . 2004,第9期

机译：通过C-H···pi和N···H-O-H···N相互作用水合手性C_2-对称双二茂铁亚胺的自组装
2. Self-assemblies of chiral p-haloaryl sulfoxides through C-H center dot center dot center dot O short contacts and halogen involving interactions [J] . Naso F, Cardellicchio C, Capozzi MAM, New Journal of Chemistry . 2006,第12期

机译：通过C-H中心点中心点中心点O点短接触与涉及相互作用的卤素的手性对卤代芳基亚砜的自组装
3. Chiral self-assembly of methyltin(IV)-naproxenates: Combining dative Sn-O bonds, secondary Sn center dot center dot center dot O interactions and C-H center dot center dot center dot O hydrogen bonding to make an inter-helical meander-shaped network [J] . Deak A, Tarkanyi G Journal of Organometallic Chemistry . 2006,第8期

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4. Preparation of Novel C_2-Symmetric Chiral Bicyclo2.2.2octadiene Ligands and Their Use for Rhodium-Catalyzed Asymmetric 1,4-Addition of Arylboronic Acids [C] . Yusuke Otomaru, Kazuhiro Okamoto, Kazuhito Ueyama, Symposium on Organometallic Chemistry . 2004

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5. Understanding the effects of pressure on biological self-assembly: Role of hydration and water-mediated interactions. [D] . Sarupria, Sapna. 2009

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6. Supramolecular Chirality in Azobenzene-Containing Polymer System: Traditional Postpolymerization Self-Assembly Versus In Situ Supramolecular Self-Assembly Strategy [O] . Xiaoxiao Cheng, Tengfei Miao, Yilin Qian, 2020

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机译：两对二氢苯并吡唑并喹唑啉的同分异构体：中心对称二聚体，链和由C-H中心点中心点中心点N和C-H中心点中心点中心点pi（arene）氢键和pi-pi堆积相互作用构建的链

Self-assembly of a hydrated chiral C_2-symmetric bisferrocenylimine via C-H···pi and N···H-O-H···N interactions

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