Copper(II) with a novel tris(3,5-diisopropyl-1-pyrazolyl)methane ligand,[Cu(X_2){HC(3,5-~iPr_2pz)_3}] (X=Cl and NO_3)

Kiyoshi Fujisawa; Tetsuya Ono; Hijiri Aoki; Yoko Ishikawa; Yoshitaro Miyashita; Ken-ichi Okamoto; Hiroshi Nakazawa; Hideyuki Higashimura

首页> 外文期刊>Inorganic Chemistry Communications >Copper(II) with a novel tris(3,5-diisopropyl-1-pyrazolyl)methane ligand,[Cu(X_2){HC(3,5-~iPr_2pz)_3}] (X=Cl and NO_3)

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Copper(II) with a novel tris(3,5-diisopropyl-1-pyrazolyl)methane ligand,[Cu(X_2){HC(3,5-~iPr_2pz)_3}] (X=Cl and NO_3)

机译：具有新型三（3,5-二异丙基-1-吡唑基）甲烷配体[Cu（X_2）{HC（3,5-〜iPr_2pz）_3}]的铜（II）（X = Cl和NO_3）

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摘要

The synthesis of a novel tris(3,5-diisopropyl-1-pyrazolyl)methane ligand,HC(3,5-~iPr_2pz)_3,is described;the structures of chlorocopper(II) and nitratocopper(II0 complexes with its ligand have been determined by X-ray crystallography and compared with those of the related copper(II) complexes wtih HB(3,5-~iPr_2pz)_3~-.

机译：描述了一种新型的三（3,5-二异丙基-1-吡唑基）甲烷配体HC（3,5-〜iPr_2pz）_3的合成;氯铜（II）和硝基铜（II0）配合物的结构具有通过X射线晶体学测定，并与HB（3,5-〜iPr_2pz）_3〜-的相关铜（II）配合物进行比较。

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来源
《Inorganic Chemistry Communications》 |2004年第3期|共3页
作者
Kiyoshi Fujisawa; Tetsuya Ono; Hijiri Aoki; Yoko Ishikawa; Yoshitaro Miyashita; Ken-ichi Okamoto; Hiroshi Nakazawa; Hideyuki Higashimura;
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正文语种 eng
中图分类无机化学;
关键词
copper(II); hydrotris(pyrazolyl)borate; tris(pyrazolyl)methane; mononuclear complex; crystal structure;

机译：铜（II）;氢三（吡唑基）硼酸盐;三（吡唑基）甲烷;单核络合物;晶体结构;

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1. Copper(II) with a novel tris(3,5-diisopropyl-1-pyrazolyl)methane ligand,[Cu(X_2){HC(3,5-~iPr_2pz)_3}] (X=Cl and NO_3) [J] . Kiyoshi Fujisawa, Tetsuya Ono, Hijiri Aoki, Inorganic Chemistry Communications . 2004,第3期

机译：具有新型三（3,5-二异丙基-1-吡唑基）甲烷配体[Cu（X_2）{HC（3,5-〜iPr_2pz）_3}]的铜（II）（X = Cl和NO_3）
2. Synthesis and structural characterization of a mixed-ligand diiron(II) complex formed by a linked bitopic tris(pyrazolyl)methane ligand: {HC(3,5-Me(2)pz)(3)Fe[mu-p-C6H4(CH2OCH2C(pz)(3))(2)]Fe(3,5-Me(2)pz)(3)CH }(BF4)(4) (pz = pyrazolyl ring) [J] . Reger DL, Little CA, Semeniuc RF, Inorganica Chimica Acta . 2009,第1期

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机译：双（3,5-二异丙基-1-吡唑基）甲烷连接的单核和双核铜（I）配合物：对带有中性配位体的三配位铜（I）配合物的基本配位化学的认识
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机译：Diaqua的晶体结构（314-二乙基-261317-四氮酸酐16.4.0.0712二甲磺酸）铜（II）（314-二乙基-261317-四氮酸酐十二糖果烷烃）铜（II）四溴化铜二水合物Cu（C22H44N4）（H 2 O）2 Cu（C22H44N4） Br4·2H2O
7. Synthesis and Characterization of Catecholato Copper(II) Complexes with Sterically Hindered Neutral and Anionic N3 Type Ligands: Tris(3,5-diisopropyl-1-pyrazolyl)methane and Hydrotris(3,5-diisopropyl-1-pyrazolyl)borate [O] . Kiyoshi Fujisawa, Tetsuya Ono, Moemi Okamura 2020

机译：具有空间阻碍中性和阴离子N3型配体的儿茶醇铜（II）配合物的合成与表征：Tris（3,5-二异丙基-1-吡唑基）甲烷和水溶式（3,5-二异丙基-1-吡唑基）硼酸盐

Copper(II) with a novel tris(3,5-diisopropyl-1-pyrazolyl)methane ligand,[Cu(X_2){HC(3,5-~iPr_2pz)_3}] (X=Cl and NO_3)

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