Triethylene glycol ether end-grafted carbosilane dendrimers:synthesis and complexation behaviour

Roy Buschbeck; Heinrich Lang

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Triethylene glycol ether end-grafted carbosilane dendrimers:synthesis and complexation behaviour

机译：三乙二醇醚接枝碳硅烷树枝状大分子：合成与络合行为

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The synthesis of first and second generation carbosilane dendrimers with end-grafted triethylene glycol methyl ether units is reported.The reaction chemistry of Me_2Si(CH_2CH_2CH_2SiMe_2CH_2(CH_2CH_2O)_4Me)_2 (4),Si(CH_2CH_2CH_2SiMe_2CH_2(CH_2 CH_2O)_4Me)_4 (5) and Si(CH_2CH_2CH_2SiMe(CH_2CH_2CH_2SiMe_2CH_2(CH_2CH_2O)_4Me)_2)_4 (7) towards alkali metal ions is described.ESI-TOF studies reveal that in 4 one,in 5 two and in 7 up to four metal ions can be trapped,which enables 4,5 and 7 as possible ionophores for chemical sensors.

机译：报道了带有末端接枝的三乙二醇甲基醚单元的第一代和第二代碳硅烷树状大分子的合成.Me_2Si（CH_2CH_2CH_2SiMe_2CH_2（CH_2CH_2O）_4Me）_2（4），Si（CH_2CH_2CH_2SiMe_2CH_2（CH_2 CH_2O）_4Me）_4（5 ）和Si（CH_2CH_2CH_2SiMe（CH_2CH_2CH_2SiMe_2CH_2（CH_2CH_2O）_4Me）_2）_4（7）中描述的碱金属离子。ESI-TOF研究表明，在4个1、5个2和7中最多可以捕获4个金属离子，这使得4,5和7可能是化学传感器的离子载体。

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《Inorganic Chemistry Communications》 |2004年第11期|共4页
作者
Roy Buschbeck; Heinrich Lang;
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正文语种 eng
中图分类无机化学;
关键词
carbosilane dendrimers; chemical sensors; hydrosilylation; metallodendrimers; triethylene glycol ether;

机译：碳硅烷树状大分子;化学传感器;氢化硅烷化;金属树状大分子;三甘醇醚;

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1. Triethylene glycol ether end-grafted carbosilane dendrimers:synthesis and complexation behaviour [J] . Roy Buschbeck, Heinrich Lang Inorganic Chemistry Communications . 2004,第11期

机译：三乙二醇醚接枝碳硅烷树枝状大分子：合成与络合行为
2. Carbosilane dendrimers with end-grafted silacrown- and crown-ether units [J] . Buschbeck R, Lang H, Agarwal S, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2004,第8期

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3. SYNTHESIS AND AQUEOUS SOLUTION PROPERTIES OF AMPHIPHILIC DIBLOCK COPOLYMERS BASED ON METHYL TRIETHYLENE GLYCOL VINYL ETHER AND BENZYL VINYL ETHER [J] . Forder C., Armes SP., Billingham NC., Macromolecules . 1997,第19期

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5. Synthesis and characterization of novel amphiphilic networks based on poly(ethylene glycol) and poly(benzyl ether) dendrimers. [D] . Zhu, Chao. 2003

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Triethylene glycol ether end-grafted carbosilane dendrimers:synthesis and complexation behaviour

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