Discernibel apical coordination in mu_3-oxo-bridged mixed metal trinuclear carboxylate [Fe_2MnO(CHCl-2COO)_6(THF)_2H_2O]

Sergiu Shova; Denis Prodius; Valeriu Mereacre; Yurii A.Simonov; Janusz Lipkowski; Constantin Turta

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Discernibel apical coordination in mu_3-oxo-bridged mixed metal trinuclear carboxylate [Fe_2MnO(CHCl-2COO)_6(THF)_2H_2O]

机译：mu_3-氧代桥联的三核金属羧酸盐[Fe_2MnO（CHCl-2COO）_6（THF）_2H_2O]的顶基配位。

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Novel mu_3-oxo-bridged heterotrinuclear iron(III)-manganese9II0 carboxylate of the composition [Fe_2MnO(CHCl_2COO)_6 (THF)_2H_2O] has been ysnthesized and characterized by X-ray crystallography,IR and TG.The positional parameters of the various metal ions within trinuclear [Fe_2MnO]~(6+) core were determined unambiguously due to their different coordination environment and hydrogen bonds forming between two H_2O molecules coordinated to Mn ions in different clusters.

机译：合成了具有[Fe_2MnO（CHCl_2COO）_6（THF）_2H_2O]组成的新型mu_3-氧桥杂三核铁（III）-锰9II0羧酸盐，并通过X射线晶体学，IR和TG表征。由于三氟[Fe_2MnO]〜（6+）的配位环境不同，并且在不同簇中与Mn离子配位的两个H_2O分子之间形成氢键，因此确定了三核[Fe_2MnO]〜（6+）核中的离子。

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《Inorganic Chemistry Communications》 |2004年第2期|共4页
作者
Sergiu Shova; Denis Prodius; Valeriu Mereacre; Yurii A.Simonov; Janusz Lipkowski; Constantin Turta;
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正文语种 eng
中图分类无机化学;
关键词
iron(III) manganese(II) beterocluster; crystal structure; hydrogen bonding;

机译：铁（III）锰（II）球簇;晶体结构;氢键;

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1. Discernibel apical coordination in mu_3-oxo-bridged mixed metal trinuclear carboxylate [Fe_2MnO(CHCl-2COO)_6(THF)_2H_2O] [J] . Sergiu Shova, Denis Prodius, Valeriu Mereacre, Inorganic Chemistry Communications . 2004,第2期

机译：mu_3-氧代桥联的三核金属羧酸盐[Fe_2MnO（CHCl-2COO）_6（THF）_2H_2O]的顶基配位。
2. Analogy of the Coordination Chemistry of Alkaline Earth Metal and Lanthanide Ln~(2+) Ions: The Isostructural Zoo of Mixed Metal Cages [IM(OtBu)_4{Li(thf)}_4(OH)] (M = Ca, Sr, Ba, Eu), [MM'_6(OPh)_8(thf)_6] (M = Ca, Sr, Ba, Sm, Eu, M' = Li, Na), and t [J] . William Maudez, Markus Meuwly, Katharina M. Fromm Chemistry: A European journal . 2007,第29期

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Discernibel apical coordination in mu_3-oxo-bridged mixed metal trinuclear carboxylate [Fe_2MnO(CHCl-2COO)_6(THF)_2H_2O]

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