Transition metal complexes with thiosemicarbazide-based ligands.XLIV.The supramolecular arrangement in the Ni(II)complexes of S-methylisothiosemicarbazide

Sladjana B.Novakovic; Goran Al.Bogdanovic; Vukadin M.Leovac

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Transition metal complexes with thiosemicarbazide-based ligands.XLIV.The supramolecular arrangement in the Ni(II)complexes of S-methylisothiosemicarbazide

机译：过渡金属配合物与硫代氨基脲基配体.XLIV.S-甲基异硫代氨基脲镍（II）配合物的超分子排列

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The reaction of the octahedral complex[Ni(ITSC)_2(NO_3)_2](1)with sodium terephthalate yielded the novel octahedral complex[Ni(ITSC)_2(H_2O)_2](tere)(centre dot)2H_2O(2),(ITSC = S-methylisothiosemicarbazide,tere = terephthalate dianion).The X-ray structural analysis of the starting and the final compound showed that they have a centrosymmetric octahedral geometry with the NiN_4O_2 chromophore.As a result of the non-covalent intermolecular interactions,molecules of both complexes tend to associate into the characteristic 2D blocks separated by S-methyl moieties.In the case of 2,the terephthalate anions,located between the S-methyl groups,enable the transformation of the 2D into 3D supramolecular structure.The similar structural arrangement is also found in two previously published structures.

机译：八面体络合物[Ni（ITSC）_2（NO_3）_2]（1）与对苯二甲酸钠的反应产生了新型八面体络合物[Ni（ITSC）_2（H_2O）_2]（叔）（中心点）2H_2O（2），（ITSC = S-甲基异硫代氨基脲，tere =对苯二甲酸二阴离子）。起始和最终化合物的X射线结构分析表明，它们具有NiN_4O_2发色团的中心对称八面体几何结构。这是非共价分子间相互作用的结果，这两种配合物的分子往往会结合到由S-甲基部分隔开的2D嵌段中。在2的情况下，位于S-甲基之间的对苯二甲酸阴离子使2D转变为3D超分子结构。在两个先前公开的结构中也发现了类似的结构布置。

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《Inorganic Chemistry Communications》 |2005年第1期|共5页
作者
Sladjana B.Novakovic; Goran Al.Bogdanovic; Vukadin M.Leovac;
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正文语种 eng
中图分类无机化学;
关键词
Nickel(II)complexes; S-methylisothiosemicarbazide; 2D supramolecular block; X-ray analysis; Supramolecular structure;

机译：镍（II）配合物;S-甲基异硫代氨基脲;二维超分子嵌段;X射线分析;超分子结构;

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1. Transition metal complexes with thiosemicarbazide-based ligands.XLIV.The supramolecular arrangement in the Ni(II)complexes of S-methylisothiosemicarbazide [J] . Sladjana B.Novakovic, Goran Al.Bogdanovic, Vukadin M.Leovac Inorganic Chemistry Communications . 2005,第1期

机译：过渡金属配合物与硫代氨基脲基配体.XLIV.S-甲基异硫代氨基脲镍（II）配合物的超分子排列
2. Transition metal complexes with thiosemicarbazide-based ligands. Part LIV. Nickel(II) complexes with pyridoxal semi- (PLSC) and thiosemicarbazone (PLTSC). Crystal and molecular structure of [Ni(PLSC)(H2O)(3)](NO3)(2) and [Ni(PLTSC-H)py]NO3 [J] . Leovac VM, Jovanovic LS, Divjakovic V, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第26期

机译：过渡金属配合物与基于硫代氨基脲的配体。第五部分镍（II）与吡ido醛半（PLSC）和硫代半碳环素（PLTSC）形成复合物。 [Ni（PLSC）（H2O）（3）]（NO3）（2）和[Ni（PLTSC-H）py] NO3的晶体和分子结构
3. Transition metal complexes with thiosemicarbazide-based ligand - Part LV: Synthesis and X-ray structural study of novel Ni(II) complexes with pyridoxal semicarbazone and pyridoxal thiosemicarbazone [J] . Leovae VM, Jovanovic LS, Jevtovic VS, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第13期

机译：含硫代氨基脲的配体的过渡金属配合物-第LV部分：吡ido醛氨基脲和吡x醛硫代氨基脲的新型Ni（II）配合物的合成和X射线结构研究
4. Metallo-supramolecular Diblock Copolymers based on Heteroleptic Cobalt(III) and Nickel(II) Bis-terpyridine Complexes [C] . Clement Mugemana, Pierre Guillet, Stephanie Hoeppener, American Chemical Society . 2010

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机译：过渡金属配合物的X射线晶体学研究：I.协同选择性混合金属配合物；二。铜（II）-四硫杂环丁烷和-四氮杂-甲基。
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机译：5-三氟甲基四唑阴离子与一些二价过渡金属离子形成的配合物的研究。一些取代苯甲酸铜（Ⅱ）配合物的磁化学和光谱研究。具有取代的吡啶n-氧化物的铜（II）卤化物配合物

Transition metal complexes with thiosemicarbazide-based ligands.XLIV.The supramolecular arrangement in the Ni(II)complexes of S-methylisothiosemicarbazide

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