Diaquabis(4,4'-bipyridine)copper(II) di(o-sulfobenzimidate) dichloromethane solvate, a two-dimensional Cu_4(4,4'-C_5H_4NC_5H_4N)_4 rhombic grid clathrating guest dichloromthane

Pance Naumov; Gligor Jovanovski; John V.Hanna; Ibrahim Abdul Razak; Suchada Chantrapromma; Hoong-Kun Fun; Seik Weng Ng

首页> 外文期刊>Inorganic Chemistry Communications >Diaquabis(4,4'-bipyridine)copper(II) di(o-sulfobenzimidate) dichloromethane solvate, a two-dimensional Cu_4(4,4'-C_5H_4NC_5H_4N)_4 rhombic grid clathrating guest dichloromthane

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Diaquabis(4,4'-bipyridine)copper(II) di(o-sulfobenzimidate) dichloromethane solvate, a two-dimensional Cu_4(4,4'-C_5H_4NC_5H_4N)_4 rhombic grid clathrating guest dichloromthane

机译：双（4,4'-联吡啶）铜（II）二（邻磺基苯甲二酸酯）二氯甲烷溶剂化物，二维Cu_4（4,4'-C_5H_4NC_5H_4N）_4菱形网格笼罩客体二氯甲烷

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In the crystal structure of bis(4,4'-bipyridine)diaquacopper(II) di(o-sulfobenzimidate) dichloromthane solvate, the host poly-cationic [Cu(4,4'-C_5H_4NC_5H_4N)_2(H_2O)]_infinity rhombic grids stack over each other 8.16 A apart along the c-axis of the orthorhombic Pbcn unit cell. The Cu_4(4,4'-bpy)_4 rhombus clathrating a disordered dichloromethane molecule has a copper atom at the corner and the spacer heterocycle with pyridyl rings twisted by 21.8(2) deg, as its side. The anions occupy the space between the layers; the grids interact with each other indirectly through water-anion hydrogen bonds [O…O = 2.766(4); O…N = 3.061(4) A]. The structure sets a remarkable example of potentials born by the polyfunctional o-sulfobenzimidate moiety for construction of unusual architectures.

机译：在双（4,4'-联吡啶）双铜（II）二氯邻甲磺酸二氯甲烷溶剂化物的晶体结构中，主体聚阳离子[Cu（4,4'-C_5H_4NC_5H_4N）_2（H_2O）] _无穷大菱形网格沿正交Pbcn晶胞的c轴彼此堆叠8.16A。笼罩着无序二氯甲烷分子的Cu_4（4,4'-bpy）_4菱形在边角处有一个铜原子，而侧边有吡啶基环扭曲21.8（2）度的间隔杂环。阴离子占据了层之间的空间。网格通过水-阴离子氢键间接相互作用[O…O = 2.766（4）; O…N = 3.061（4）A]。该结构树立了一个杰出的例子，说明多官能邻磺基苯甲二酸酯部分具有潜在的构造异常结构的潜力。

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《Inorganic Chemistry Communications》 |2001年第12期|共3页
作者
Pance Naumov; Gligor Jovanovski; John V.Hanna; Ibrahim Abdul Razak; Suchada Chantrapromma; Hoong-Kun Fun; Seik Weng Ng;
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正文语种 eng
中图分类无机化学;基本无机化学工业;
关键词
bipyridine; clathrate; host-guest complex; saccharin; spacers; X-ray diffraction;

机译：联吡啶;包合物;宿主-客体复合物;糖精;间隔物;X射线衍射;

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1. Diaquabis(4,4'-bipyridine)copper(II) di(o-sulfobenzimidate) dichloromethane solvate, a two-dimensional Cu_4(4,4'-C_5H_4NC_5H_4N)_4 rhombic grid clathrating guest dichloromthane [J] . Pance Naumov, Gligor Jovanovski, John V.Hanna, Inorganic Chemistry Communications . 2001,第12期

机译：双（4,4'-联吡啶）铜（II）二（邻磺基苯甲二酸酯）二氯甲烷溶剂化物，二维Cu_4（4,4'-C_5H_4NC_5H_4N）_4菱形网格笼罩客体二氯甲烷
2. Synthesis and Structural Features of [4,4 '-Diisopropoxyester-2,2 '-bipyridine],[Dichloro(4,4 '-diisopropoxyester-2,2 '-bi-pyridine)platinum(ii)] and Its Dichloromethane Solvated Pseudo-Polymorph: Versatile Supramolecular Interactions [J] . Browning Charles, Nesterov Vladimir N., Wang Xiaoping, Journal of chemical crystallography . 2015,第6期

机译：[4,4'-二异丙氧基酯-2,2'-联吡啶]，[二氯（4,4'-二异丙氧基酯-2,2'-联吡啶）铂（ii）]的合成和结构特征及其在二氯甲烷中的伪溶液-多晶型物：多功能超分子相互作用
3. Hydrogen-bonding orgainzation of (4,4) coordination layers into a 3-D molecular architecture with channels clathrating guest molecules [Cu(tdc)(bpy)(H_2O)](bpy) (tdc=thiophine-2,5-dicarboxylate;bpy=4,4'-bipyridine) [J] . Xian-Zhong Sun, Yi-Feng Sun, Bao-Hui Ye, Inorganic Chemistry Communications . 2003,第11期

机译：（4,4）配位层的氢键键合成3D分子结构，其通道包裹客体分子[Cu（tdc）（bpy）（H_2O）]（bpy）（tdc = thiophine-2,5-dicarboxylate; bpy = 4,4'-联吡啶）
4. Investigation of magnetic properties in the case of three families of 1-dimensional magnets: M(II)A(4,4'-bipyridine); M = iron, cobalt, nickel, copper; A = chloride, nitrogen, (ox). [D] . Danilovic, Dusan S. 2010

机译：研究三族一维磁体的磁性能：M（II）A（4,4'-bipyridine）; M =铁，钴，镍，铜； A =氯，氮（ox）。
5. Poly[bis(4,4′-bipyridine)(μ3-4,4′-dicarboxybiphenyl-3,3′-dicarboxylato)iron(II)] [O] . Qun-Hui Meng, Hui-Ling Lai, Han Lu, 2016

机译：聚[双（4,4'-联吡啶）（μ3-4,4'-二羧基联苯-3,3'-二羧基）铁（II）]
6. catena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ2N:N′] 4,4′-bipyridine solvate] [O] . Rufu Yao, Dong E. Wang 2009

机译：系列聚[[二水合二（thiocyanato-＆安培;＃954; N）钴（II）] - ＆安培;＃956; -4,4'-安培;＃8242; -bipyridine-＆安培;＃954; 2N：N＆安培;＃8242; ] 4,4＆amp;＃8242; -bipyridine solvate]

Diaquabis(4,4'-bipyridine)copper(II) di(o-sulfobenzimidate) dichloromethane solvate, a two-dimensional Cu_4(4,4'-C_5H_4NC_5H_4N)_4 rhombic grid clathrating guest dichloromthane

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