...
首页> 外文期刊>Inorganic Chemistry Communications >Template synthesis and characterization of hexaaza macrocycles containing pyridine iron(II) complex nanoparticles dispersed within nanoreactors of zeolite-Y
【24h】

Template synthesis and characterization of hexaaza macrocycles containing pyridine iron(II) complex nanoparticles dispersed within nanoreactors of zeolite-Y

机译:含吡啶铁(II)配合物纳米颗粒分散在沸石-Y纳米反应器中的六氮杂大环的模板合成与表征

获取原文
获取原文并翻译 | 示例
           

摘要

Iron(II) complexes with 18- and 20-membered hexaaza macrocyclic ligands were entrapped in the nanoreactors of zeolite-Y by a two-step process in the liquid phase: (i) adsorption of [bis(diamine)iro-n(II)] (diamine = 1,2-diaminoethane, 1,3-diaminopropane, 1,2-diaminobenzene, 1,3-diaminobenzene); [Fe(N-N)_2]~(2+)-NaY; in the nanoreactors of the zeolite, and (ii) template condensation of the iron(II) precursor complex with 2,6-diacetylpyridine.The mode of bonding and overall geometry of the complexes and new complex nanoparticles entrapped in the nanoreactor of zeolite-Y ([Fe([18 or 20]py2N4)]~(2+) NaY, [Fe(Bzo2[18 or 20]py2N4)]~(2+)-NaY) has been inferred through FT-1R, TGA, XRD, XPS spectroscopic techniques and elemental analysis as well as nitrogen adsorption.
机译:具有18和20元六氮杂大环配体的铁(II)配合物在液相中通过两步过程被包裹在沸石Y的纳米反应器中:(i)吸附[双(二胺)iro-n(II)的吸附)](二胺= 1,2-二氨基乙烷,1,3-二氨基丙烷,1,2-二氨基苯,1,3-二氨基苯); [Fe(N-N)_2]〜(2 +)-NaY;在沸石的纳米反应器中,以及(ii)铁(II)前体配合物与2,6-二乙酰基吡啶的模板缩合。配合物的结合模式和整体几何形状以及包裹在沸石-Y纳米反应器中的新配合物纳米粒子([Fe([18或20] py2N4)]〜(2+)NaY,[Fe(Bzo2 [18或20] py2N4)]〜(2 +)-NaY已通过FT-1R,TGA,XRD推断,XPS光谱技术和元素分析以及氮吸附。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号