Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally functionalized acetylferroceneoxime: Crystal and molecular structures of [C5H5FeC5H4C(H3)=NO]2SbPh3 and C5H5FeC5H4C(CH3)=NOH

Handong Yin; Li Quan; Linwei Li

首页> 外文期刊>Inorganic Chemistry Communications >Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally functionalized acetylferroceneoxime: Crystal and molecular structures of [C5H5FeC5H4C(H3)=NO]2SbPh3 and C5H5FeC5H4C(CH3)=NOH

【24h】

Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally functionalized acetylferroceneoxime: Crystal and molecular structures of [C5H5FeC5H4C(H3)=NO]2SbPh3 and C5H5FeC5H4C(CH3)=NOH

机译：具有内部功能化的乙酰基二茂铁肟的三苯基锑（V）配合物的合成，光谱和结构方面：[C5H5FeC5H4C（H3）= NO] 2SbPh3和C5H5FeC5H4C（CH3）= NOH的晶体和分子结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Triorganoantimony(V) complex (C5H5FeC5H4C(CH3)=NO)2SbPh3 (1) has been prepared by the reaction of Ph3SbCl2 with acetylferroceneoxime C5H5FeC5H4C(CH3)=NOH (2) in 1:2 molar ratio in anhydrous toluene. The complexes have been characterized by elemental analyses, IR and NMR (~1H and ~(13)C) spectroscopic studies, and biologic activity was measured. And crystal structures of 1, 2 were reported. The coordination geometry around the antimony atom in 1 was slightly distorted trigonal bipyramidal with, the carbon atoms of the SbPh3 unit in equatorial positions and the two oxygen atoms of the oxime group occupying axial positions. The free oxime was clearly hydrogen bonded (H-N 2.10 A/2.04 A in 2) to essentially form a dimer.

机译：三有机锑（V）络合物（C5H5FeC5H4C（CH3）= NO）2SbPh3（1）是通过Ph3SbCl2与乙酰基二茂铁肟C5H5FeC5H4C（CH3）= NOH（2）在无水甲苯中的摩尔比反应制得的。该复合物已通过元素分析，IR和NMR（〜1H和〜（13）C）光谱研究进行了表征，并测定了生物活性。并且报道了1、2的晶体结构。 1中锑原子周围的配位几何结构略微扭曲为三角形双锥体，SbPh3单元的碳原子位于赤道位置，肟基的两个氧原子位于轴向位置。游离肟显然是氢键合的（H-N 2.10 A / 2.04 A in 2），基本上形成二聚体。

著录项

来源
《Inorganic Chemistry Communications》 |2008年第10期|共4页
作者
Handong Yin; Li Quan; Linwei Li;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类无机化学;
关键词
Organoantimony(V)oximates; Oxime; Thermogravimetric analysis; Antitumor activity; Crystal structure;

机译：肟酸;肟;热重分析;抗肿瘤活性;晶体结构;

相似文献

外文文献
中文文献
专利

1. Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally functionalized acetylferroceneoxime: Crystal and molecular structures of [C5H5FeC5H4C(H3)=NO]2SbPh3 and C5H5FeC5H4C(CH3)=NOH [J] . Handong Yin, Li Quan, Linwei Li Inorganic Chemistry Communications . 2008,第10期

机译：具有内部功能化的乙酰基二茂铁肟的三苯基锑（V）配合物的合成，光谱和结构方面：[C5H5FeC5H4C（H3）= NO] 2SbPh3和C5H5FeC5H4C（CH3）= NOH的晶体和分子结构
2. Synthetic, spectroscopic and structural aspects of triphenylantimony(V) complexes with internally functionalized oximes: crystal and molecular structure of [Ph3Sb{ON=C(Me)C5H4N-2}(2)] [J] . Gupta A., Sharma RK., Bohra R., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第23期

机译：具有内部功能化肟的三苯基锑（V）配合物的合成，光谱和结构方面：[Ph3Sb {ON = C（Me）C5H4N-2}（2）]的晶体和分子结构
3. Synthesis, spectroscopic and structural aspects of some tetraorganodistannoxanes with internally functionalized oxime. 2. Crystal and molecular structure of [{Me2Sn(ON=C(Me)C5H4N)}(2)O}](2)center dot 2[2-NC5H4(Me)C=NOH] [J] . Sharma V., Sharma RK., Bohra R., Journal of Organometallic Chemistry . 2002,第1a2期

机译：某些具有内部功能化肟的四有机二锡氧烷的合成，光谱和结构方面。 2. [{Me2Sn（ON = C（Me）C5H4N）}（2）O}]（2）中心点2 [2-NC5H4（Me）C = NOH]的晶体和分子结构
4. SPECTROSCOPIC AND THEORETICAL STUDY ON THE STRUCTURES AND DYNAMICS OF FUNCTIONAL MOLECULES - TOWARDS AN UNDERSTANDING OF THE MOLECULAR RECOGNITION FOR ENCAPSULATION COMPLEXES [C] . TAKAYUKI EBATA, RYOJI KUSAKA, YOSHIYA INOKUCHI, International Symposium on Molecular Spectroscopy . 2011

机译：函数分子结构与动力学的光谱与理论研究 - 朝向对封装复合物分子识别的认识
5. The preparation, structures and spectroscopic properties of binuclear rhodium complexes and [platinum(phosphorus hydrogen oxygen)]/viologen systems: Time-resolved photocrystallography and the study of photoinduced intermolecular electron transfer. [D] . Gerlits, Oksana O. 2005

机译：双核铑配合物和[铂（磷氢氧）] /紫精体系的制备，结构和光谱性质：时间分辨光晶体学和光致分子间电子转移的研究。
6. Synthesis, Characterization and Thermal Studies of Zn(II), Cd(II) and Hg(II) Complexes of N-Methyl-N-Phenyldithiocarbamate: The Single Crystal Structure of [(C6H5)(CH3)NCS2]4Hg2 [O] . Damian C. Onwudiwe, Peter A. Ajibade 1995

机译：N-甲基-N-苯基二硫代氨基甲酸酯的Zn（II），Cd（II）和Hg（II）配合物的合成，表征和热研究：[（C6H5）（CH3）NCS2] 4Hg2的单晶结构
7. The Syntheses, Properties, and Crystal and Molecular Structures of the Lanthanoid Mixed-Complexes ofO,O′-Diisopropyl Dithiophosphate and Dimethyl Sulfoxide: Ln{(C3H7O)2PS2}3{(CH3)2SO}2 (Ln=La or Nd), and Eu{(C3H7O)2PS2}2{(CH3)2SO}3Eu{(C3H7O)2PS2}4 [O] . Takashi Imai, Masao Nakamura, Kiyofumi Nagai, 1986

机译：镧混合络合物的合成，性质和晶体和晶体和分子结构，O'-二异丙基二硫代磷酸二甲基二甲基二甲基磷酸酯：Ln（C3H7O）2PS2} 3（（CH3）2SO} 2（Ln = La或Nd ）和eu {（c3h7o）2ps2} 2 {（ch3）2so} 3 eu {（c3h7o）2ps2} 4
8. Crystal and Molecular Structure of (Ni((CH3)2C(OH)CH2COCH3)2) (Ni(NCS)4(P(CH2CH2CN)3)2): A Beta-Hydroxyketone Chelate Complex. [R] . Foxman, B. M., Mazurek, H. 1978

机译：（Ni（（CH3）2C（OH）CH2COCH3）2）（Ni（NCs）4（p（CH2CH2CN）3）2）的晶体和分子结构：β-羟基酮螯合物。

Synthesis, spectroscopic and structural aspects of triphenylantimony(V) complex with internally functionalized acetylferroceneoxime: Crystal and molecular structures of [C5H5FeC5H4C(H3)=NO]2SbPh3 and C5H5FeC5H4C(CH3)=NOH

摘要

著录项

相似文献

相关主题

期刊订阅