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首页> 外文期刊>Inorganic Chemistry Communications >The structures, solvent-free synthesis and interconversions of the complexes [MC12(CEAP)2] and their hydrogen-bonded salts [CEAPHfelMCU] {M = Zn, Co and Hg, CEAP = 4-[N,N-bis(2-cyanoethyl)amino]pyridine}
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The structures, solvent-free synthesis and interconversions of the complexes [MC12(CEAP)2] and their hydrogen-bonded salts [CEAPHfelMCU] {M = Zn, Co and Hg, CEAP = 4-[N,N-bis(2-cyanoethyl)amino]pyridine}

机译：配合物[MC12（CEAP）2]及其氢键盐[CEAPHfelMCU] {M = Zn，Co和Hg，CEAP = 4- [N，N-bis（2-氰乙基）氨基]吡啶}

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Discrete metal complexes, [MC12(CEAP)2] {M = Zn (1), Co (2) and Hg (3), CEAP = 4-[N,N-bis(2-cyanoethyl) amino]pyridine} and their hydrogen-bonded salts [CEAPH]2[MCl4] {M = Zn (4), Co (5) and Hg (6), CEAPH = 4-[N,N-bis(2-cyanoethyl)amino]pyridium} were prepared using CEAP or CEAP·HCl ligands and metal chlorides (molar ratio = 2:1) by both solvent-thermal synthesis method and solvent-free method. The crystal structure and powder X-ray diffraction (PXDR) studies revealed that the discrete metal complexes 1-3 could be converted into their hydrogen-bonded salts 4-6 respectively by absorbing HCl vapor in solid-gas station and these salts except for 6 could be converted back to their corresponding discrete metal complexes by grinding with KOH in solid station.
机译：离散金属络合物，[MC12（CEAP）2] {M = Zn（1），Co（2）和Hg（3），CEAP = 4- [N，N-双（2-氰基乙基）氨基]吡啶}及其化合物制备了氢键盐[CEAPH] 2 [MCl4] {M = Zn（4），Co（5）和Hg（6），CEAPH = 4- [N，N-双（2-氰基乙基）氨基]吡啶鎓}通过溶剂-热合成法和无溶剂法使用CEAP或CEAP·HCl配体和金属氯化物（摩尔比= 2：1）。晶体结构和粉末X射线衍射（PXDR）研究表明，离散的金属配合物1-3可以通过在固体加气站吸收HCl蒸气分别转化为氢键盐4-6，而这些盐除了6通过在固体站中用KOH研磨可以转化回其相应的离散金属络合物。

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