Crystalline and molecular structures of anhydrous lanthanide perchlorates Ln(ClO4)(3) with Ln = La, Ce, Pr, Sm, Eu, Ho, Er, Tm, and Lu

Pascal JL.; Cunin F.; Fitch A.; Vaughan G.; Favier F.

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Crystalline and molecular structures of anhydrous lanthanide perchlorates Ln(ClO4)(3) with Ln = La, Ce, Pr, Sm, Eu, Ho, Er, Tm, and Lu

机译：Ln = La，Ce，Pr，Sm，Eu，Ho，Er，Tm和Lu的无水镧系高氯酸盐Ln（ClO4）（3）的晶体和分子结构

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The anhydrous perchlorates Ln(ClO4)(3), where ClO4 is coordinated to Ln atoms (Ln = La, Ce, Pr, Sm, Eu, Ho, Er, Tm, and Lu) crystallize in two distinct groups of isostructural species, Rietveld refinements show that from lanthanum to thulium (low temperature form), the crystal system is hexagonal(space group P6(3)/m, Z = 2) with 9.400(3) Angstrom < a < 9.201(1) Angstrom and 5.918(1) Angstrom < c < 5.563(1) Angstrom. The Rietveld refinement converged to R-F = 0.033, R-p = 0.029, and R-wp = 0.053 for Eu(ClO4)(3), The channeled structure is built on the basis of slightly distorted tricaped trigonal Eu centered prisms of nine oxygen atoms belonging to nine tridentate [ClO4]. Thullium thigh temperature form) and lutetium crystallize in trigonal R3c unit cells (Z = 6) with, respectively, a = 8.13286(2) Angstrom, c = 24.1586(1) Angstrom, and a 8.11559(4) Angstrom, c = 24.0047(1) Angstrom. For Lu(ClO4)(3), R-F, R-p, and R-wp mere 0.039, 0.046, and 0.061, respectively, Its molecular structure consists of infinite layers of Lu atoms in a tricaped trigonal antiprism surrounding of oxygens. Layers and linkages between layers are ensured by simultaneously bridging and chelating tridentate [ClO4](3). (C) 1998 Academic Press. [References: 30]

机译：无水高氯酸盐Ln（ClO4）（3），其中ClO4与Ln原子配位（Ln = La，Ce，Pr，Sm，Eu，Ho，Er，Tm和Lu）在两个不同的同构物种群Rietveld中结晶精炼表明，从镧到（（低温形式），晶体系统是六方晶系（空间群P6（3）/ m，Z = 2），具有9.400（3）埃<9.201（1）埃和5.918（1））

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《International Journal of Quantum Chemistry》 |1998年第2期|共7页
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Pascal JL.; Cunin F.; Fitch A.; Vaughan G.; Favier F.;
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中图分类物理化学（理论化学）、化学物理学;
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Powder diffraction; Complexes; Behavior;

机译：粉末衍射;复合物;行为;

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1. Crystalline and molecular structures of anhydrous lanthanide perchlorates Ln(ClO4)(3) with Ln = La, Ce, Pr, Sm, Eu, Ho, Er, Tm, and Lu [J] . Pascal JL., Cunin F., Fitch A., International Journal of Quantum Chemistry . 1998,第2期

机译：Ln = La，Ce，Pr，Sm，Eu，Ho，Er，Tm和Lu的无水镧系高氯酸盐Ln（ClO4）（3）的晶体和分子结构
2. Thermodynamic Functions of Complex Zirconia Based Lanthanide Oxides-Pyrochlores Ln(2)Zr(2)O(7) (Ln = La, Pr, Sm, Eu, Gd) and Fluorites Ln(2)O(3) center dot 2ZrO(2) (Ln = Tb, Ho, Er, Tm) [J] . Russian Journal of Inorganic Chemistry . 2019,第10期

机译：基于氧化锆的镧系元素氧化物的热力学功能 - 氧化酯 - 甘油LN（2）Zr（2）O（7）（LN = La，Pr，Sm，Eu，Gd）和氟物Ln（3）o（3）中心点2zro（2 ）（ln = tb，ho，er，tm）
3. Syntheses and crystal structures of rare earth basic nitrates hydrates Part III. [Ln_6(mu_6-O)(mu_3-OH)_8(H_2O)_(12)(eta~2-NO_3)_6](NO_3)_2 centre dot xH_2O, Ln = Y, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu; x = 3,4,5, 6 [J] . Gerald Giester, Zdirad Zak, Peter Unfried Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics . 2009,第1a2期

机译：稀土碱式硝酸盐的合成和晶体结构水合第三部分。 [Ln_6（mu_6-O）（mu_3-OH）_8（H_2O）_（12）（eta〜2-NO_3）_6]（NO_3）_2中心点xH_2O，Ln = Y，Sm，Eu，Gd，Tb，Dy ，Ho，Er，Tm，Yb，Lu; x = 3,4,5，6
4. Heavily doped oxygen-ion conducting Ln2+xTi2-xO7-δ-(Ln=Ho-Lu; x=0.44-0.81) pyrochlores: Crystal structure, microstructure and electrical conductivity [C] . International conference on solid state ionics . 2008

机译：重掺杂的氧离子导电LN2 + XTI2-XO7-Δ-（LN = HO-LU; x = 0.44-0.81）晶体结构，微观结构和电导率
5. Experimental and thermodynamic investigation of RE-Mg-Zn (RE=Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) systems [D] . Zhu, Zhijun. 2015

机译：RE-Mg-Zn（RE = Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb和Lu）系统的实验和热力学研究
6. Sensors for optical thermometry based on luminescence from layered YVO4: Ln3+ (Ln = Nd Sm Eu Dy Ho Er Tm Yb) thin films made by atomic layer deposition [O] . Michael N. Getz, Ola Nilsen, Per-Anders Hansen -1

机译：基于层状YVO4发光的光学测温传感器：Ln3 +（Ln3 = NdSmEuDyHoErTmYb）通过原子层沉积制成的薄膜
7. Template synthesis, crystal structure and luminescent properties of neutral N4O3 tripodal LnIIIL complexes (Ln III = La3+, Eu3+, Gd3+, Tb 3+, Dy3+, Ho3+, Er3+, Tm3+ or Lu3+; H3L = Tris{3′-(2″- pyridyl)-5′-tert-butyl-2′-hydroxybenzylidene-2-iminoethyl}amine) [O] . Wong WK, Liang H, Guo J, 2004

机译：中性N4O3三脚架LnIIIL配合物（Ln III = La3 +，Eu3 +，Gd3 +，Tb 3 +，Dy3 +，Ho3 +，Er3 +，Tm3 +或Lu3 +的模板合成，晶体结构和发光特性; H3L = Tris {3'-（2''-吡啶基）-5'-叔丁基-2'-羟基亚苄基-2-亚氨基乙基}胺）

Crystalline and molecular structures of anhydrous lanthanide perchlorates Ln(ClO4)(3) with Ln = La, Ce, Pr, Sm, Eu, Ho, Er, Tm, and Lu

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