New Possibilities of OD ESR: Vacuum Ultraviolet Generation of Radical Ion Pairs

O. A. Anisimov; V. N. Verkhovlyuk; S. B. Zikirin; A. G. Matveeva; S. I. Trashkeev; Yu. N. Molin

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New Possibilities of OD ESR: Vacuum Ultraviolet Generation of Radical Ion Pairs

机译：OD ESR的新可能性：真空紫外产生自由基离子对

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A new version of the optically detected electron spin resonance (OD ESR) technique using vacuum ultraviolet radiation to generate radical ion pairs is discussed. The technique can be used to study the spin-correlated processes of charge recombination in thin films that can be useful in spintronics. Distinctive features of photoionization and high-energy (including X-ray) ionization are discussed. The first results obtained by the technique in the study of charge recombination in polymeric and liquid crystal films are presented. The results of the concurrent observation of the OD ESR and electron cyclotron resonance (ECR) in the low-pressure gas over the sample are outlined. A possible application of ECR in the context of the OD ESR spectroscopy is suggested.

机译：讨论了使用真空紫外线辐射产生自由基离子对的光学检测电子自旋共振（OD ESR）技术的新版本。该技术可用于研究薄膜中与自旋相关的电荷复合过程，这可用于自旋电子学。讨论了光电离和高能（包括X射线）电离的显着特征。介绍了该技术在聚合物和液晶薄膜中电荷复合研究中获得的第一个结果。概述了同时观察样品上低压气体中的OD ESR和电子回旋共振（ECR）的结果。建议将ECR应用于OD ESR光谱学。

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《Applied Magnetic Resonance》 |2014年第9期|共12页
作者
O. A. Anisimov; V. N. Verkhovlyuk; S. B. Zikirin; A. G. Matveeva; S. I. Trashkeev; Yu. N. Molin;
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正文语种 eng
中图分类磁性弛豫及共振现象;
关键词
Possibilities; Vacuum; Ultraviolet;

机译：可能性;真空;紫外线;

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1. New Possibilities of OD ESR: Vacuum Ultraviolet Generation of Radical Ion Pairs [J] . O. A. Anisimov, V. N. Verkhovlyuk, S. B. Zikirin, Applied Magnetic Resonance . 2014,第9期

机译：OD ESR的新可能性：真空紫外产生自由基离子对
2. Generation of hydroxyl radicals during photodegradation of chloroacetic acids by 254 nm ultraviolet: A special degradation process revealed by a holistic radical determination methodology [J] . Wang Lei, Chen Yi, Chen Baiyang, Journal of Hazardous Materials . 2021,第Pta2期

机译：254nm紫外线光降解期间羟基自由基产生羟基乙酸：通过整体自由基测定方法显示的特殊降解过程
3. Hydroxyl radical generation with a high power ultraviolet light emitting diode (UV-LED) and application for determination of hydroxyl radical reaction rate constants [J] . Takeda Kazuhiko, Fujisawa Katsunari, Nojima Hitoshi, Journal of Photochemistry and Photobiology, A. Chemistry . 2017,第期

机译：具有高功率紫外发光二极管（UV-LED）的羟基自由基，以及用于测定羟基自由基反应速率常数的应用
4. ESR study of photodecomposition mechanism of a long-lived radical perfluoro-2,4-dimethly-3, ESR spectrum of trifluoromethyl radical formed during solid-phase photodecomposition at 77 K in glassy matrix [C] . S. R. Allayarov, D. A. Gordon Asia Pacific Electron Paramagnetic Resonance/Electron Spin Resonance Symposium . 2002

机译：长寿命自氟-2,4-二硫-2,4-二硫-2,4-二硫-3，在玻璃基质中的固相光分解期间形成的三氟甲基ESR光谱的光致基团的ESR研究
5. The vacuum ultraviolet laser photochemistry of CO2 molecule and threshold photoelectron studies of hydrocarbon radicals by velocity-map imaging method. [D] . Lu, Zhou. 2015

机译：利用速度图成像方法研究了CO2分子的真空紫外激光光化学和碳氢化合物自由基的阈值光电子研究。
6. An in vivo ESR spin-trapping study: Free radical generation in rats from formate intoxication— role of the Fenton reaction [O] . Anna E. Dikalova, Maria B. Kadiiska, Ronald P. Mason 2001

机译：体内ESR自旋诱捕研究：甲酸中毒在大鼠体内产生自由基-Fenton反应的作用
7. Role of OH radicals in the formation of oxygen molecules following vacuum ultraviolet photodissociation of amorphous solid water. [O] . Hama Tetsuya, Yokoyama Masaaki, Yabushita Akihiro, 2010

机译：OH自由基在无定形固体水真空紫外光解离后在氧分子形成中的作用。
8. Non-linear effects in the radiolysis-optically detected ESR of radical-ion pairs in liquid and glassy solutions. Reactions and motion of organic radicals as studied by ESR and OD ESR spectroscopy [R] . Antzutkin, O. 1992

机译：辐射分解中的非线性效应 - 光学检测液体和玻璃状溶液中自由基离子对的EsR。通过EsR和OD EsR光谱研究有机基团的反应和运动

New Possibilities of OD ESR: Vacuum Ultraviolet Generation of Radical Ion Pairs

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