A Single-Crystal EPR Study at 95 GHz of the Type-2 Copper Site of Nitrite Reductase From Alcaligenes faecalis

Scarpelli F.; Arrieta A. L.; Gast P.; Groenen E. J. J.; Milikisyants S.; Murphy M. E. P.; Huber M.

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A Single-Crystal EPR Study at 95 GHz of the Type-2 Copper Site of Nitrite Reductase From Alcaligenes faecalis

机译：粪便产碱菌亚硝酸盐还原酶的2型铜位点在95 GHz处的单晶体EPR研究

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An electron spin echo-detected electron paramagnetic resonance study has been performed on the type-2 copper site of the nitrite reductase from Alcaligenes faecalis. The experiment on a single crystal at 95 GHz has allowed the determination of the complete g tensor. This includes the orientations of the principal axes of three g tensors in the asymmetric unit of the unit cell with respect to the crystallographic axes. The orientation with respect to the crystallographic axes has been translated into the orientation of the g tensor in the type-2 copper site. The corresponding electronic structure is discussed in relation to the enzymatic function of this copper site.

机译：电子自旋回波检测电子顺磁共振研究已在粪便拟南芥中亚硝酸还原酶的2型铜位点上进行。在95 GHz的单晶上进行的实验可以确定完整的g张量。这包括在晶胞的不对称单元中三个g张量的主轴相对于结晶轴的取向。相对于晶轴的取向已转换为2型铜位中g张量的取向。关于该铜位点的酶功能，讨论了相应的电子结构。

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《Applied Magnetic Resonance》 |2015年第4期|共10页
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Scarpelli F.; Arrieta A. L.; Gast P.; Groenen E. J. J.; Milikisyants S.; Murphy M. E. P.; Huber M.;
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1. A Single-Crystal EPR Study at 95 GHz of the Type-2 Copper Site of Nitrite Reductase From Alcaligenes faecalis [J] . Scarpelli F., Arrieta A. L., Gast P., Applied Magnetic Resonance . 2015,第4期

机译：粪便产碱菌亚硝酸盐还原酶的2型铜位点在95 GHz处的单晶体EPR研究
2. A Single-Crystal Electron Paramagnetic Resonance Study at 95 GHz of the Type 1 Copper Site of the Green Nitrite Reductase of Alcaligenes faecalis [J] . M. van Gastel, M. J. Boulanger, G. W. Canters, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2001,第11期

机译：粪便产碱菌绿色亚硝酸盐还原酶的1型铜位在95 GHz的单晶电子顺磁共振研究
3. A Single-Crystal Electron Paramagnetic Resonance Study at 95 GHz of the Type 1 Copper Site of the Green Nitrite Reductase of Alcaligenes faecalis [J] . M.van Gastel, M.J.Boulanger, G.W.Canters, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2001,第11期

机译：粪便产碱菌绿色亚硝酸盐还原酶的1型铜位在95 GHz的单晶电子顺磁共振研究
4. STRUCTURAL, MECHANISTIC AND SPECTROSCOPIC STUDIES OF SPINACH NITRITE REDUCTASE [C] . Masakazu Hirasawa, Sofya Kuznetsova, Pierre Setif, International Congress of Photosynthesis . 2005

机译：菠菜亚硝酸盐还原酶的结构，机械和光谱研究
5. Copper -nitrosyl formation by nitrite reductase [D] . Tocheva, Elitza I. 2007

机译：亚硝酸还原酶形成亚硝基铜
6. Single-Crystal EPR Study at 95 GHz of the Type 2 Copper Site of the Inhibitor-Bound Quercetin 23-Dioxygenase [O] . Maria Fittipaldi, Roberto A. Steiner, Michio Matsushita, 2003

机译：抑制剂结合型槲皮素23-二加氧酶2型铜位点在95 GHz的单晶EPR研究
7. Directing the mode of nitrite binding to a copper-containing nitrite reductase from Alcaligenes faecalis S-6: Characterization of an active site isoleucine [O] . Boulanger, Martin J., Murphy, Michael E.P. 2003

机译：指导亚硝酸盐粪便S-6中亚硝酸盐与含铜亚硝酸盐还原酶结合的模式：活性位点异亮氨酸的表征

A Single-Crystal EPR Study at 95 GHz of the Type-2 Copper Site of Nitrite Reductase From Alcaligenes faecalis

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