Synthesis and characterization of gallium complexes bearing 4-alkyl-2,6-bis(aryliminomethylene)-phenol ligands; crystal structure of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium

Gu WJ; Shen YZ; Li YZ; Pan Y; Zhu CJ

首页> 外文期刊>Inorganica Chimica Acta >Synthesis and characterization of gallium complexes bearing 4-alkyl-2,6-bis(aryliminomethylene)-phenol ligands; crystal structure of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium

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Synthesis and characterization of gallium complexes bearing 4-alkyl-2,6-bis(aryliminomethylene)-phenol ligands; crystal structure of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium

机译：带有4-烷基-2,6-双（亚芳基亚甲基）-苯酚配体的镓配合物的合成与表征;二甲基[4-甲基-2,6-双-（对甲基苯基亚氨基亚甲基）-苯酚基]镓的晶体结构

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Eight new dimethylgallium complexes bearing 4-alkyl-2.6-bis(aryliminomethlene))-phenol ligands of type Me2GaL (L = 4-methyl-2, 6-bis-(phenyliminomethylene)-phenolato (3); L = 4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phejiolato (4); L = 4-methyl-2,6-bis-(1-naphthyliminomethylene)- phenolato (5); L = 4-methyl-2,6-bis-(2-chlorophenyliminomethylene)-phenolato (6); 4-tert-butyl-2,6-bis(phenyliminomethylene)-phenolato (7); L = 4-tert-butyl-2.6-bis-)-methylphenyliminomethylene)-phenolato (8); L = 4-tert-butyl-2,6bis-(1-naphthyliminomethylene)-phenolato (9); and L = 4-tert-butyl-2,6-bis-(2-chlorophenyliminomethylene)-phenolato](3) have been synthesized by the reaction of trimethylgallium with appropriate phenol. The complexes obtained have been characterized by elemental analysis, 'H NMR, IR and mass spectroscopy, respectively. The solid-state structures of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium (4) have been determined by X-ray single crystal analysis. In the structure, Ga atom is coordinated by one nitrogen atom and the other nitrogen atom remains constant. The distorted tetrahedron geometry around gallium is presented. (c) 2006 Elsevier B.V. All rights reserved.

机译：八个新的带有Me2GaL类型的4-烷基-2.6-双（芳基亚甲基）苯酚配体的二甲基镓配合物（L = 4-甲基-2，6-双-（苯基亚氨基亚甲基）-苯酚基（3）; L = 4-甲基- 2,6-双-（对甲基苯基亚氨基亚甲基）-邻苯二酚（4）; L = 4-甲基-2,6-双-（1-萘基亚氨基亚甲基）-苯酚（5）; L = 4-甲基-2,6-双-（2-氯苯基亚氨基亚甲基）-苯酚基（6）; 4-叔丁基-2,6-双（苯基亚氨基亚甲基）-苯酚基（7）; L = 4-叔丁基-2.6-双-）-甲基苯基亚氨基亚基）-酚（8）; L = 4-叔丁基-2,6双-（1-萘基亚甲基）-苯酚基（9）; L ＝ 4-叔丁基-2，6-双-（2-氯苯基亚氨基亚甲基）-苯酚基]（3）是通过三甲基镓与适当的苯酚反应合成的。获得的配合物已分别通过元素分析，1 H NMR，IR和质谱进行了表征。二甲基[4-甲基-2,6-双-（对甲基苯基亚氨基亚甲基）-苯酚基]镓（4）的固态结构已通过X射线单晶分析确定。在该结构中，Ga原子由一个氮原子配位，而另一个氮原子保持恒定。呈现了镓周围扭曲的四面体几何形状。（c）2006 Elsevier B.V.保留所有权利。

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《Inorganica Chimica Acta》 |2006年第5期|共5页
作者
Gu WJ; Shen YZ; Li YZ; Pan Y; Zhu CJ;
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中图分类生物体其他化学成分;
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trimethylgallium; 4-alkyl-2; 6-bis(aryliminomethlene)-phenol; X-ray crystallography; ALPHA; BETA-UNSATURATED IMIDES; DERIVATIVES; TRIMETHYLGALLIUM; EPOXIDES; GROUP-13;

机译：三甲基镓;4-烷基-2;6-双（芳基次甲基）-苯酚;X射线晶体学;阿尔法;贝塔不饱和酰亚胺;衍生物;三甲基镓;环氧化合物;组别13;

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1. Synthesis and characterization of gallium complexes bearing 4-alkyl-2,6-bis(aryliminomethylene)-phenol ligands; crystal structure of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium [J] . Gu WJ, Shen YZ, Li YZ, Inorganica Chimica Acta . 2006,第5期

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2. Synthesis, characterization and luminescence study of dimethyl[2-(arylmethyleneimino)phenolato] gallium complexes: Crystal structure of dimethyl[N-(4-N,N '-dimethylamino) phenylmethyleneiminophenolato]gallium [J] . Shen YZ, Wang Y, Zhang YY, Journal of Organometallic Chemistry . 2007,第24期

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Synthesis and characterization of gallium complexes bearing 4-alkyl-2,6-bis(aryliminomethylene)-phenol ligands; crystal structure of dimethyl[4-methyl-2,6-bis-(p-methylphenyliminomethylene)-phenolato]gallium

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