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Mossbauer spectroscopy on the surface of Mars: constraints and expectations

机译:火星表面的Mossbauer光谱:约束和期望

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摘要

Mossbauer spectrometers will be included on the upcoming MER/Athena and Mars Express/Beagle rovers. These instruments have the exciting potential to characterize the surface mineralogy of Mars, but there are several complicating factors. It is difficult to differentiate minerals with similar structures, particularly if the rock or soil is multimineralic and the peaks overlap. Mineral modes cannot be determined from Mossbauer spectra alone. The temperature dependence of Mossbauer parameters for common rock-forming minerals and glasses is known for only a few minerals, but it is strong. No database of Mars surface temperature Mossbauer spectra of minerals or glasses currently exists, with which Martian data can be compared. Peak areas in Mossbauer spectroscopy do not directly correspond to the abundances of the minerals that give rise to them, and the calibration/correction factors to compensate for this problem are currently known for only a few minerals. We assess here the advantages and disadvantages of Mossbauer spectroscopy for remote data acquisition, and describe work currently under way in our laboratory to address these potential complications.
机译:Mossbauer光谱仪将包括在即将到来的MER / Athena和Mars Express / Beagle流浪者中。这些仪器具有表征火星表面矿物学的令人兴奋的潜力,但是有一些复杂的因素。很难区分结构相似的矿物,特别是如果岩石或土壤是多矿物的且峰重叠时。不能仅通过Mossbauer光谱确定矿物模式。常见的岩石形成矿物和玻璃的Mossbauer参数的温度依赖性仅针对少数几种矿物而为人所知,但它很强。目前尚无矿物或玻璃的火星表面温度Mossbauer光谱数据库,可以与火星数据进行比较。 Mossbauer光谱中的峰面积并不直接对应于产生这些峰的矿物的丰度,并且目前仅针对少数几种矿物已知用于补偿该问题的校准/校正因子。我们在这里评估Mossbauer光谱用于远程数据采集的优缺点,并描述目前在我们实验室中为解决这些潜在并发症而开展的工作。

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