Use of a fluoride ion selective electrode as a tool for monitoring relatively fast kinetic processes. Applications to the hydrolysis of organofluorophosphorus esters and 2,4-dinitrofluorobenzene

Moutiers G.; Villien L.; Terrier F.; Le Guevel E.

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Use of a fluoride ion selective electrode as a tool for monitoring relatively fast kinetic processes. Applications to the hydrolysis of organofluorophosphorus esters and 2,4-dinitrofluorobenzene

机译：使用氟离子选择性电极作为监测相对快速的动力学过程的工具。在有机氟磷酸酯和2,4-二硝基氟苯的水解中的应用

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Experimental conditions have been designed which allowed the use of a fluoride ion selective electrode for the monitoring of reactions that proceed with a moderately fast departure of F- ion, i.e., t(1/2) approximate to 30 seconds, in aqueous solution. The procedure applied in particular to the S(N)A(R) substitution of 1-fluoro-2,4-dinitrobenzene with p-chlorophenoxide ion and to the hydrolysis, catalyzed by oximate ions, of three organofluorophosphorus esters, namely sarin, soman and diisopropylphosphorofluoridate (DFP). Depending upon the system at hand, the required buffering of the solutions can be made up from the nucleophile reagent itself or through the use of an external buffer. [References: 33]

机译：设计了实验条件，该条件允许使用氟离子选择性电极来监测在水溶液中以适度快速离开F离子进行的反应，即t（1/2）约30秒。该方法特别适用于用对氯苯氧离子对S1-N-2-A取代1-氟-2,4-二硝基苯的S（N）A（R）以及由氧肟酸根离子催化的三种有机氟磷酸酯的水解，即沙林，梭曼和二氟磷酸二异丙酯（DFP）。取决于手头的系统，溶液的所需缓冲液可以由亲核试剂本身或通过使用外部缓冲液组成。 [参考：33]

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《Electroanalysis》 |2000年第17期|共5页
作者
Moutiers G.; Villien L.; Terrier F.; Le Guevel E.;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
Fluoride ion selective electrode; Oximate ion reactivity; Kinetics; Organofluorophosphorus esters; Sarin; Soman; Insecticides; Diisopropylphosphorofluoridate; Quaternary-salts; Reactivity; 2-lt; (hydroxyimino)methylgt; imidazole; Dephosphorylation; Decontamination; Reactivators; Detector; Mixtures; Halides; Invitro;

机译：氟离子选择性电极;氧离子反应性;动力学;有机氟代磷酸酯;沙林;索曼;杀虫剂;氟代磷酸二异丙酯;季盐;反应性;2-（羟基亚氨基）甲基咪唑;去磷酸化;去污;活化剂;检测剂;混合物体外;

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1. Use of a fluoride ion selective electrode as a tool for monitoring relatively fast kinetic processes. Applications to the hydrolysis of organofluorophosphorus esters and 2,4-dinitrofluorobenzene [J] . Moutiers G., Villien L., Terrier F., Electroanalysis . 2000,第17期

机译：使用氟离子选择性电极作为监测相对快速的动力学过程的工具。在有机氟磷酸酯和2,4-二硝基氟苯的水解中的应用
2. Use of a chloride ion selective electrode as a tool for monitoring relatively fast kinetic processes. Application to the hydrolysis of yperite analogues in presence of oximate nucleophiles [J] . Rodrigues SP., Toullec J., Moutiers G., Analusis: Chimie Analytique - Methodes Physiques d'Analyse . 2000,第6期

机译：使用氯离子选择性电极作为监测相对快速的动力学过程的工具。在肟酸亲核试剂存在下用于水解堇青石类似物
3. Kinetic study and analytical applications of micellar catalyzed reactions of 1-fluoro-2,4-dinitrobenzene with inorganic thioanions using a fluoride-selective electrode [J] . Gerakis Athanasios M. Talanta: The International Journal of Pure and Applied Analytical Chemistry . 2000,第4期

机译：氟选择电极的1-氟-2,4-二硝基苯与无机硫代阴离子的胶束催化反应的动力学研究和分析应用
4. Phase-Transfer Catalytic Asymmetric Hydrolysis and Alcoholysis of α-Chiral Esters via Dynamic Kinetic Resolution [C] . Eiji Yamamoto, Kodai Wakafuji, Yuho Furutachi 日本化学会春季年会講演予稿集 . 2018

机译：通过动态动力学分辨率相转移催化不对称水解和α-手性酯的醇解
5. Development of a converging wall-jet instrument and its use to measure the dynamic response of the fluoride ion-selective electrode to fluoride and halide interferent ions [D] . Clay, Michael L. 1996

机译：会聚壁喷射仪的开发及其在测量氟离子选择电极对氟离子和卤离子干扰物的动态响应中的用途
6. Monitoring of Diisopropyl Fluorophosphate Hydrolysis by Fluoride-Selective Polymeric Films Using Absorbance Spectroscopy [O] . Madhumati Ramanathan, Lin Wang, James R. Wild, -1

机译：通过氟化物选择性的聚合物膜使用吸收光谱二异丙基氟水解的监测
7. Selective spectrophotometric determination of some primary amines using 2,4-dinitrofluorobenzene reagent [O] . Theia’a N. Al-Sabha, Intisar A. Hamody 2015

机译：2,4-二硝基氟苯试剂选择性分光光度法测定某些伯胺

Use of a fluoride ion selective electrode as a tool for monitoring relatively fast kinetic processes. Applications to the hydrolysis of organofluorophosphorus esters and 2,4-dinitrofluorobenzene

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