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Large amplitude AC voltammetry - A comparison between theory and experiment

机译：大振幅交流伏安法-理论与实验的比较

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Recently a published theory advocates the abandonment of the classical limitation that the applied voltage signal, V, in reversible AC voltammetry, be small compared with RTF: We have performed experiments designed to test the validity of the theoretical predictions. The AC voltammetric peak heights and areas have been measured as a function of V. for both the fundamental and harmonic frequencies. As well, the shapes of the AC voltammograms have been compared with predictions. In general, experiment agrees well with theory Though our experiments have not yet addressed a range of concentrations, they do have strong implications for electroanalytical applications of AC voltammetry. [References: 15]
机译：最近，一个已发表的理论提倡摒弃经典的限制，即与RT / nF相比，可逆交流伏安法中施加的电压信号V要小：我们已经进行了旨在验证理论预测有效性的实验。对于基频和谐波频率，交流伏安峰高和峰面积均作为V.的函数进行了测量。同样，交流伏安图的形状已经与预测进行了比较。总体而言，实验与理论基本吻合尽管我们的实验尚未解决一系列浓度问题，但它们确实对交流伏安法的电分析应用具有重要意义。 [参考：15]

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