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Voltammetric determination of phenylglyoxylic acid in urine using graphite composite electrode

机译:石墨复合电极伏安法测定尿液中的苯乙醛酸

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摘要

A composite electrode prepared from graphite powder and epoxy resin was applied as a working electrode for the determination of phenlglyoxylic acid (one of the metabolites of styrene) in human urine. Cathodic differential pulse stripping voltammetry was used and optimum conditions have been found giving the limit of determination about 5 mg L-1. All results were compared with those obtained using hanging mercury drop electrode. For the confirmation of suggested mechanism of the electrochemical reaction the elimination voltammetry with linear scan Was used.
机译:将由石墨粉和环氧树脂制成的复合电极用作工作电极,用于测定人尿中的苯二酸(苯乙烯的代谢产物之一)。使用阴极差分脉冲溶出伏安法,已找到最佳条件,给出了约5 mg L-1的测定极限。将所有结果与使用悬挂式汞滴电极获得的结果进行比较。为了证实所建议的电化学反应机理,使用了具有线性扫描的消除伏安法。

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