Electrochemiluminescence based on solid state tri(4,7-diphenyl-1,10-phenanthroline) ruthenium(ii) ditetrakis(4-chlorophenyl) borate immobilized on carbon fibers

Liu C.; Dai J.; Yang L.; Jiang P.; Chen Y.; Xiao D.

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Electrochemiluminescence based on solid state tri(4,7-diphenyl-1,10-phenanthroline) ruthenium(ii) ditetrakis(4-chlorophenyl) borate immobilized on carbon fibers

机译：基于固态三（4,7-二苯基-1,10-菲咯啉）钌（ii）二四（4-氯苯基）硼酸酯固定在碳纤维上的电化学发光

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A simple method for immobilization of tri(4,7-diphenyl-1,10-phenanthroline) ruthenium(II) ditetrakis(4-chlorophen-yl) borate ([Ru(dpp)_3][(4-Clph)_4B]_2) on carbon fiber electrodes was developed. Excellent electrochemical activity and electrochemiluminescence (ECL) signal of the coated carbon fiber electrodes were observed using oxalate as the co-reactant. In addition, the effects of pH, scan rate, nitrogen and oxygen on ECL intensity were also studied. To demonstrate the reliability, the coated carbon fiber electrodes were used as ECL detectors and very low concentration of phenol was detectable (5.0 x 10~~8 M).

机译：一种固定三（4,7-二苯基-1,10-菲咯啉）钌（II）二四（4-氯酚基）硼酸钌（[Ru（dpp）_3] [（4-Clph）_4B] _2 ）在碳纤维电极上开发。使用草酸盐作为共反应剂，观察到碳纤维电极的电化学活性和电化学发光（ECL）信号优异。此外，还研究了pH，扫描速率，氮气和氧气对ECL强度的影响。为了证明可靠性，将涂层碳纤维电极用作ECL检测器，可检测到非常低的苯酚浓度（5.0 x 10 ~~ 8 M）。

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《Electroanalysis》 |2010年第12期|共5页
作者
Liu C.; Dai J.; Yang L.; Jiang P.; Chen Y.; Xiao D.;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
ru(dpp)3(4-clph)4b2; Carbon fiber; Electrochemiluminescence; Oxalate; Phenol;

机译：[ru（dpp）3] [（4-clph）4b] 2;碳纤维;电化学发光;草酸盐;苯酚;

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1. Electrochemiluminescence based on solid state tri(4,7-diphenyl-1,10-phenanthroline) ruthenium(ii) ditetrakis(4-chlorophenyl) borate immobilized on carbon fibers [J] . Liu C., Dai J., Yang L., Electroanalysis . 2010,第12期

机译：基于固态三（4,7-二苯基-1,10-菲咯啉）钌（ii）二四（4-氯苯基）硼酸酯固定在碳纤维上的电化学发光
2. Electrochemically generated chemiluminescence of tris (2,2 '-bipyridine) ruthenium(II), tris(1,10-phenathroline)ruthenium(II) and tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) complexes [J] . Kapturkiewicz A., Szrebowaty P. Journal of the Chemical Society. Dalton Transactions . 2002,第16期

机译：三（2,2'-联吡啶）钌（II），三（1,10-菲咯啉）钌（II）和三（4,7-二苯基-1,10-菲咯啉）钌（II）络合物的电化学化学发光
3. Optical Sensing Material for Dissolved Oxygen: Covalent Immobilization of Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) Complex in Sol-Gels [J] . Yong Chae Jeong, Ok-Jae Sohn, Jong Il Rhee Bulletin of the Korean Chemical Society . 2007,第5期

机译：溶解氧的光学传感材料：三（4,7-二苯基-1,10-菲咯啉）钌（II）络合物在溶胶-凝胶中的共价固定
4. Effect of catalyst on the fluorescence quenching of Tris (4, 7-diphenyl-1, 10-phenanthroline) ruthenium (II) dichloride for dissolved oxygen detection [C] . Mahmud Zulkifli, Herman Sukreen Hana, Noor Uzer Mohd, IEEE Regional Symposium on Micro and Nano Electronics . 2013

机译：催化剂对Tris（4，7-diphenyl-1，10-phenththroline）钌（II）二氯化钌荧光猝灭的影响，用于溶解氧检测
5. Optimization and application of photoluminescence-following electron-transfer with tris(tetramethyl-1,10-phenanthroline) Os/Ru(III) complexes and Fenton based chemiluminescence detection of NSAIDs and dopamine in biological samples. [D] . Patel, Mohit Pratish. 2016

机译：三（-1,10-菲咯啉）Os / Ru（III）配合物和基于Fenton的化学发光法检测生物样品中的NSAID和多巴胺后电子转移的优化和应用。
6. cis-Bis(O-methyldithiocarbonato-κ2SS′)bis(triphenylphosphane-κP)ruthenium(II) [O] . Cintya Valerio-Cárdenas, Simón Hernández-Ortega, Reyna Reyes-Martínez, 2013

机译：cis-Bis（O-methyldithiocarbonato-κ2SS）双（三苯基膦-κP）钌（II）
7. Efficient and Stable Solid-State Light-Emitting Electrochemical Cell Using Tris(4, 7-diphenyl-1, 10-phenanthroline)ruthenium(II) Hexafluorophosphate [O] . -1

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8. Excited-State Acid-Base Reactions of Dicyanobis(2,2'-bipyridine)ruthenium(II) and Dicyanobis(1,10-phenanthroline)ruthenium(II) [R] . Peterson, S. H., Demas, J. N. 1978

机译：双氰基（2,2'-联吡啶）钌（II）和二氰基双（1,10-菲咯啉）钌（II）的激发态酸碱反应

Electrochemiluminescence based on solid state tri(4,7-diphenyl-1,10-phenanthroline) ruthenium(ii) ditetrakis(4-chlorophenyl) borate immobilized on carbon fibers

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