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Behavior of Glassy Carbon Paste Electrode in Flowing Methanolic Solutions

机译:流动性甲醇溶液中玻碳糊状电极的行为

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摘要

Carbon paste electrodes are often used for electrochemical determinations, but their application in media with high content of organic solvents, particularly in HPLC, is limited by their low stability. The work presented here examines the effect of a moving methanol-containing solution on a glassy carbon paste electrode by studying its electrochemical behavior in relation to the period of contact and methanol content in the solution. In combination with microscopic observation of the paste surface it can be concluded that the electrode is affected by the methanolic solution and the surface roughness increases, resulting in the stable state compatible with measurements in highly methanolic solutions.
机译:碳糊电极通常用于电化学测定,但是其在有机溶剂含量高的介质中(尤其是在HPLC中)的应用受到其低稳定性的限制。本文介绍的工作通过研究与接触时间和溶液中甲醇含量有关的电化学行为,研究了移动的含甲醇溶液对玻璃碳糊状电极的影响。结合对糊剂表面的显微镜观察,可以得出结论,电极受甲醇溶液的影响,并且表面粗糙度增加,从而导致了与高甲醇溶液中的测量兼容的稳定状态。

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